Výsledky vyhledávání - "Nigel A. Philipson"

Reactions of hydrogen atoms in 6 mol dm–3 sulphuric acid. Part 2.—The transition from activation to diffusion control

Autor: Nigel A. Philipson, Michael J. Pilling, B. J. Holt, Frederick Sydney Dainton

Publikováno v: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 72:257

The relative rates of abstraction by hydrogen atoms of hydrogen and deuterium atoms from propan-2-ol and [2H7]propan-2-ol have been studied, as a function of temperature, in 6 mol dm–3 H2SO4, using both γ-radiation and photolysis of Fe2+ as the so

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7157b18daf686ab422e943d430c4ed54
https://doi.org/10.1039/f19767200257

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Reactions of hydrogen atoms in 6 mol dm–3 sulphuric acid. Part 1.—Temperature dependence of activation- and of diffusion-controlled reactions

Autor: Michael J. Pilling, Frederick S. Dainton, Nigel A. Philipson

Publikováno v: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 71:2377

The reactions of hydrogen atoms in 6 mol dm–3 H2SO4 have been studied over the temperature range 190–280 K, using a pulse-radiolysis technique. The reactions with Mn2+ and with propan-2-ol show Arrhenius behaviour, with rate parameters: A=(1.8 ±

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7f46a24ab8c9df1ae902565d066eabe2
https://doi.org/10.1039/f19757102377

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