Elucidation of the Structure of a Thiol Functionalized Cu-tmpa Complex Anchored to Gold via a Self-Assembled Monolayer

Autor: Longfei Wu, Daan den Boer, Dennis G. H. Hetterscheid, Nicole W. G. Smits, Jan P. Hofmann

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 58(19), 13007-13019
'Inorganic Chemistry ', vol: 58, pages: 13007-13019 (2019)
Inorganic Chemistry, 58(19), 13007-13019. American Chemical Society

The structure of the copper complex of the 6-((1-butanethiol)oxy)-tris(2-pyridylmethyl)amine ligand (Cu-tmpa-O(CH2)4SH) anchored to a gold surface has been investigated. To enable covalent attachment of the complex to the gold surface, a heteromolecu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce4b11913a55a3fa88f81c8e771232c3
http://europepmc.org/articles/PMC6784813

Covalency in Resonance-Assisted Halogen Bonds Demonstrated with Cooperativity in N-Halo-Guanine Quartets

Autor: Nicole W. G. Smits, Célia Fonseca Guerra, Lando P. Wolters

Publikováno v: Physical Chemistry Chemical Physics-PCCP, 17(3), 1585-1592. The Royal Society of Chemistry
Wolters, L P, Smits, N W G & Fonseca Guerra, C 2015, ' Covalency in Resonance-Assisted Halogen Bonds Demonstrated with Cooperativity in N-Halo-Guanine Quartets ', Physical Chemistry Chemical Physics-PCCP, vol. 17, no. 3, pp. 1585-1592 . https://doi.org/10.1039/c4cp03740e

Halogen bonds are shown to possess the same characteristics as hydrogen bonds: charge transfer, resonance assistance and cooperativity. This follows from the computational analyses of the structure and bonding in N-halo-base pairs and quartets. The o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fd781e122cd7e1455fa27d1661b88d5c
https://research.vu.nl/en/publications/a707a3f6-85a9-4302-ae0e-98e265856f33