Active Pharmaceutical Ingredient-Ionic Liquids (API-ILs): Nanostructure of the Glassy State Studied by Electron Paramagnetic Resonance Spectroscopy

Autor: Olga D. Bakulina, Mikhail Yu. Ivanov, Dmitriy V. Alimov, Sergey A. Prikhod’ko, Nicolay Yu. Adonin, Matvey V. Fedin

Publikováno v: Molecules, Vol 27, Iss 16, p 5117 (2022)

Active Pharmaceutical Ingredient-Ionic Liquids (API-ILs) draw increasing interest as a particular class of ILs that possess unusual physicochemical properties along with simultaneous potentials for pharmaceutical applications. Although nanostructurin

Externí odkaz: https://doaj.org/article/265c58a5ef3743cfb6b1f42d2c1eff69

Substitution of fluorine in M[C6F5BF3] with organolithium compounds: distinctions between O- and N-nucleophiles

Autor: Anton Yu. Shabalin, Nicolay Yu. Adonin, Vadim V. Bardin

Publikováno v: Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 703-713 (2017)

Borates M[C6F5BF3] (M = K, Li, Bu4N) react with organolithium compounds, RLi (R = Me, Bu, Ph), in 1,2-dimethoxyethane or diglyme to give M[4-RC6F4BF3] and M[2-RC6F4BF3]. When R is Me or Bu, the nucleophilic substitution of the fluorine atom at the pa

Externí odkaz: https://doaj.org/article/ed2cbec269db43f6a0e53de2d3ad7202

Inherent heterogeneities and nanostructural anomalies in organic glasses revealed by EPR

Autor: Nicolay Yu. Adonin, Dmitriy V. Alimov, Svetlana Pylaeva, Sergey A. Prikhod’ko, Olga D. Bakulina, Sergey L. Veber, Mikhail Yu. Ivanov, Matvey V. Fedin

Publikováno v: Nanoscale Advances. 3:4973-4978

Intriguing heterogeneities and nanostructural reorganizations of glassy ionic liquids (ILs) have recently been found using electron paramagnetic resonance (EPR) spectroscopy. Alkyl chains of IL cations play the key role in such phenomena and govern t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fd4821b259b8cd13cf7a2272a301ec50
https://doi.org/10.1039/d1na00452b

Peek Inside the Water Mixtures of Ionic Liquids at Molecular Level: Microscopic Properties Probed by EPR Spectroscopy

Autor: Nicolay Yu. Adonin, Igor A. Kirilyuk, Mikhail Yu. Ivanov, Yuliya F. Polienko, Matvey V. Fedin, Sergey A. Prikhod’ko

Publikováno v: International Journal of Molecular Sciences
Volume 22
Issue 21
International Journal of Molecular Sciences, Vol 22, Iss 11900, p 11900 (2021)

Many ionic liquids (ILs) can be mixed with water, forming either true solutions or emulsions. This favors their applications in many respects, but at the same time might strongly alter their physicochemical properties. A number of methods exist for s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f17b100416586007ac4757e842191410
http://europepmc.org/articles/PMC8584414

Structural Anomalies in Binary Mixtures of Ionic Liquid [Bmim]BF4 with Water Studied by EPR

Autor: Sergey A. Prikhod’ko, Nicolay Yu. Adonin, Matvey V. Fedin, Mikhail Yu. Ivanov

Publikováno v: The Journal of Physical Chemistry B. 123:9956-9962

Ionic liquids (ILs) show a variety of unusual and intriguing properties on a molecular level. Recently, a new type of structural anomaly occurring in neat ILs near their glass transition temperatures (Tg) has been found. In particular, the coexistenc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5218058e02a6aab71305aadae701a3e9
https://doi.org/10.1021/acs.jpcb.9b08933