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pro vyhledávání: '"Nicola Trathen"'
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 48(23)
A homologous series of novel trans-cyaphide–alkynyl complexes, viz. trans-[Ru(dppe)2(CP)(CCC6H4R-p)] (R = Me, H, F, CO2Me, NO2) is prepared and comprehensively characterised, alongside their parent phosphaalkyne-complex cations trans-[Ru(dppe)2(η1
Publikováno v:
Organometallics. 34:2533-2542
The ruthenaphosphaalkenyls [Ru{PCH-(SiMe2R)}Cl(CO)(PPh3)2] (R = Me, Ph, Tol) have been prepared in good yield by the facile hydroruthenation of the respective phosphaalkynes, RMe2SiCP, with [RuHCl(CO)-(PPh3)3]; all three compounds have been structura
Publikováno v:
Organometallics. 32:2501-2504
The novel ruthenaphosphaalkenyl complex [Ru{P═CH(SiMe3)}Cl(CO)(PPh3)2], prepared from [RuHCl(CO)(PPh3)3] and Me3SiC≡P, exhibits ambiphilic behavior, reacting at phosphorus with both nucleophiles and electrophiles. Its reaction with Li(pz′) or K
Publikováno v:
Dalton Transactions. 48:13101-13101
Correction for ‘Cyaphide–alkynyl complexes: metal–ligand conjugation and the influence of remote substituents’ by Samantha K. Furfari, et al., Dalton Trans., 2019, 48, 8131–8143.
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 43(24)
The novel complexes trans-[Ru(dppe)2(CCR)(CP)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis
Publikováno v:
Organometallics; Jun2015, Vol. 34 Issue 11, p2533-2542, 10p