Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Nicola G. Di Masi"'
Publikováno v:
Bioinorganic Chemistry and Applications, Vol 2, Iss 1-2, Pp 93-104 (2004)
Externí odkaz:
https://doaj.org/article/08fe00c85ffa4a2ab93f2833a7487ea4
Autor:
Luciana Maresca, Giuseppe Lorusso, Giovanni Natile, Sara de Pinto, Carmen R. Barone, Nicola G. Di Masi
Publikováno v:
Organometallics. 29:4036-4040
Two new cationic olefin complexes of platinum(II) with electron-withdrawing substituents on the allylic carbon, [PtCl(η2-CH2═CHCH2X)(tmeda)]+ (X = −C(O)OCH3 (1a), −OC(O)CH3 (1b)) have been synthesized and their reactivity toward nucleophiles i
Autor:
Nicola G. Di Masi, Luciana Maresca, Gabriella Tamasi, Sara de Pinto, Carmen R. Barone, Renzo Cini, Giovanni Natile
Publikováno v:
Inorganica Chimica Acta. 363:205-212
The reactivity of [PtCl(η2-CH2 CHR)(tmeda)]+ (R = H, 1a, or Me, 1b; tmeda = N,N,N′,N′-tetramethyl-1,2-diaminoethane) towards some ambident nucleophiles like anilines and phenolate anion has been tested. The reaction of 1a with N-methylaniline gi
Autor:
Giovanni Natile, Luciana Maresca, Nicola G. Di Masi, Giuseppe Lorusso, Concetta Pacifico, Carmen R. Barone
Publikováno v:
European Journal of Inorganic Chemistry. 2007:2144-2150
The addition products 2 of a secondary amine to a coordinated olefin, in the cationic complexes [PtCl(η2-CH2=CHR)(tmeda)]+ (tmeda = N,N,N′,N′-tetramethylethylenediamine; R = Me, 1a; Ph, 1b, H, 1c), undergo in basic medium an intramolecular nucle
Publikováno v:
Inorganic Chemistry Communications. 9:500-503
The products of addition of secondary amines to platinum(II)-coordinated terminal olefins undergo a fast Markovnikov (M)–anti-Markovnikov (anti-M) isomerization process leading, to an equilibrium composition different from that obtained under kinet
Publikováno v:
Inorganic Chemistry. 42:997-1005
Rate constants for guanine rotation about the Pt-N7 bond in (R,S,S,R)-Me(2)DABPtG(2) complexes (Me(2)DAB = N,N'-dimethyl-2,3-diaminobutane; G = 9-EtG, 3'-GMP, and 5'-GMP) were evaluated from line-shape analysis of H8 resonances. Three diastereomers,
Autor:
Luciana Maresca,§ and, Francesco Paolo Fanizzi, Nicola G. Di Masi, Giuliano Bandoli, Giovanni Natile, Alessandro Dolmella
Publikováno v:
Organometallics. 21:4595-4603
The cationic platinum complexes [Pt(η2-alkene)X(tmeda)](ClO4) (1: X = Cl, alkene = propene, 1-butene, 1-hexene; X = NO2, alkene = (E)-2-butene, (Z)-2-butene; tmeda = N,N,N‘,N‘-tetramethylethylenediamine) smoothly react with triethylamine to unde
Publikováno v:
Inorganica Chimica Acta. 325:73-78
Novel hybrid drugs, [Pt(NH 3 ) 2 (Ftorafur–H) 2 ] ( 1 ) and [Pt(NH 3 ) 2 (Furavir) 2 ](NO 3 ) 2 ( 2 ), have been prepared by reaction of Ftorafur (Ft) and Furavir (Fr) with cisplatin . Ftorafur, a prodrug of 5-fluorouracil containing a 2-tetrahydro
Publikováno v:
Inorganica Chimica Acta. 310:27-33
Different configurations of the tridentate amine ligand N,N′,N′′-trimethyldiethylenetriamine coordinated to platinum have been characterized both in the solid state and in solution. Four isomers are possible: two isomers have a mirror symmetry
Autor:
Francesco Paolo Fanizzi, Luciana Maresca,§ and, Giovanni Natile, Nicola G. Di Masi, Giuliano Bandoli, Alessandro Dolmella
Publikováno v:
Organometallics. 20:805-807
The conversion of a η2-bonded propene (complex 1) into a bridging η1,η3-allyl moiety (complex 4) is reported. The formation of 4 occurs through the following sequence of reactions: deprotonation o...