Zobrazeno 1 - 10
of 47
pro vyhledávání: '"Nico Santschi"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 2289-2294 (2018)
Cyclic benziodoxole systems have become a premier scaffold for the design of electrophilic transfer reagents. A particularly intriguing aspect is the fundamental II–IIII tautomerism about the hypervalent bond, which has led in certain cases to a su
Externí odkaz:
https://doaj.org/article/d83e0f231e9141bba3e305a5e469c769
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 1-6 (2014)
The synthesis of 5-nitro-1-(trifluoromethyl)-3H-1λ3,2-benziodaoxol-3-one (3), a hypervalent-iodine-based electrophilic trifluoromethylating reagent, is described. Whereas considerations based on cyclic voltammetry and X-ray structural properties wou
Externí odkaz:
https://doaj.org/article/03233d37385a434bbae9455e1379da73
Autor:
Nico Santschi, Antonio Togni
Publikováno v:
CHIMIA, Vol 68, Iss 6 (2014)
This account aims at providing a general overview over studies carried out in our group on 3,3-dimethyl-1-(trifluoromethyl)-3H-1?3,2-benziodaoxole (1) and 1-(trifluoromethyl)-3H-1?3,2-benziodaoxol-3-one (2). While the first part deals with the synth
Externí odkaz:
https://doaj.org/article/60a9db2c392a40eda0c0dc030c8160a5
Autor:
Tobias J. Kieser, Ryan Gilmour, Alexander Axer, Luise Nowack, Stefanie Albrecht, Gerald Kehr, Nico Santschi
Publikováno v:
ACS Chemical Neuroscience. 11:2129-2136
Gangliosides are intimately involved in a plenum of (neuro)inflammatory processes, yet progress in establishing structure-function interplay is frequently hindered by the availability of well-defined glycostructures. Motivated by the ubiquity of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::058046b15682dd656e79387285be3100
https://doi.org/10.1021/acschemneuro.0c00319
https://doi.org/10.1021/acschemneuro.0c00319
Autor:
Carmen J. Ziegler, Antonio Togni, Sebastian Kueng, Cody Ross Pitts, Nico Santschi, Ewa Pietrasiak, Dustin Bornemann, Nils Trapp
Publikováno v:
Angewandte Chemie International Edition. 58:12604-12608
The TeF5 group is significantly underexplored as a highly fluorinated substituent on an organic framework, despite it being a larger congener of the acclaimed SF5 group. In fact, only one aryl-TeF5 compound (phenyl-TeF5 ) has been reported to date, s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::02d4bdd8ef11666e584723bba275ba88
https://doi.org/10.1002/anie.201907359
https://doi.org/10.1002/anie.201907359
Autor:
Ewa Pietrasiak, Carmen J. Ziegler, Cody Ross Pitts, Antonio Togni, Nils Trapp, Nico Santschi, Dustin Bornemann, Sebastian Küng
Publikováno v:
Angewandte Chemie. 131:12734-12738
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ac26ce634927bfe9bc883a1a697b469f
https://doi.org/10.1002/ange.201907359
https://doi.org/10.1002/ange.201907359
Publikováno v:
Angewandte Chemie. 131:1970-1974
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::beac35d358d954c914531aaab45f9ace
https://doi.org/10.1002/ange.201812356
https://doi.org/10.1002/ange.201812356
Publikováno v:
Angewandte Chemie International Edition. 58:1950-1954
Modern pentafluorosulfanyl (SF5 ) chemistry has an Achilles heel: synthetic accessibility. Herein, we present the first approach to aryl-SF4 Cl compounds (key intermediates in state-of-the-art aryl-SF5 synthesis) that overcomes the reliance on hazard
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::518fd44cda3ed87fb0e8f5bdba7cd12d
https://doi.org/10.1002/anie.201812356
https://doi.org/10.1002/anie.201812356
Autor:
Elisabeth Otth, Julie Charpentier, Nico Santschi, Nils Trapp, Antonio Togni, Hans Peter Lüthi, Roland Käser, René Verel, Cody Ross Pitts, Joel Häfliger, Dustin Bornemann
Publikováno v:
Chemical Science. 10:7251-7259
We report a mild approach to the synthesis of difluoro(aryl)-λ3-iodanes (aryl-IF2 compounds) and tetrafluoro(aryl)-λ5-iodanes (aryl-IF4 compounds) using trichloroisocyanuric acid (TCICA) and potassium fluoride (KF). Under these reaction conditions,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3e610cf8eca5682e3daf7ce7c6a190a2
https://doi.org/10.1039/c9sc02162k
https://doi.org/10.1039/c9sc02162k
