Chlorination of Pu and U Metal Using GaCl3

Autor: Stephanie H. Carpenter, Bonnie E. Klamm, Taylor V. Fetrow, Brian L. Scott, Andrew J. Gaunt, Nickolas H. Anderson, Aaron M. Tondreau

Publikováno v: Inorganic Chemistry.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e1ed99fd50ed60a9cd04ef58d4926f73
https://doi.org/10.1021/acs.inorgchem.3c00522

Origin of Bond Elongation in a Uranium(IV) cis-Bis(imido) Complex

Autor: María J. Beltrán-Leiva, Matthias Zeller, Nickolas H. Anderson, Suzanne C. Bart, Tyler S. Collins, Thomas E. Albrecht-Schönzart, Cristian Celis-Barros

Publikováno v: Inorganic Chemistry. 59:18461-18468

The activation of U-N multiple bonds in an imido analogue of the uranyl ion is accomplished by using a system that is very electron-rich with sterically encumbering ligands. Treating the uranium(VI) trans-bis(imido) UI2(NDIPP)2(THF)3 (DIPP = 2,6-diis

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d18ffb1e44d9ecbad1b415bec21fbd18
https://doi.org/10.1021/acs.inorgchem.0c03340

Isolation and characterization of a californium metallocene

Autor: William J. Evans, Conrad A. P. Goodwin, Joseph M. Sperling, Thomas E. Albrecht-Schönzart, Jing Su, Stosh A. Kozimor, Lauren M. Stevens, Justin C. Wedal, Ping Yang, Frankie D. White, Zachary R. Jones, Sasha F. Briscoe, Alyssa N. Gaiser, Cory J. Windorff, Enrique R. Batista, Andrew J. Gaunt, Joseph W. Ziller, Brian L. Scott, Nickolas H. Anderson, Michael R. James, John D. Auxier, Justin N. Cross, Tener F. Jenkins, Michael T. Janicke

Publikováno v: Goodwin, C A P, Su, J, Stevens, L M, White, F D, Anderson, N H, Auxier, J D, Albrecht-Schönzart, T E, Batista, E R, Briscoe, S F, Cross, J N, Evans, W J, Gaiser, A N, Gaunt, A J, James, M R, Janicke, M T, Jenkins, T F, Jones, Z R, Kozimor, S A, Scott, B L, Sperling, J M, Wedal, J C, Windorff, C J, Yang, P & Ziller, J W 2021, ' Isolation and characterization of a californium metallocene ', Nature, vol. 599, 7885, pp. 421-424 . https://doi.org/10.1038/s41586-021-04027-8

Californium (Cf) is currently the heaviest element accessible above microgram quantities. Cf isotopes impose severe experimental challenges due to their scarcity and radiological hazards. Consequently, chemical secrets ranging from the accessibility

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e50199d4abf1dbf56d24d5404e1fcdc0
https://research.manchester.ac.uk/en/publications/e1598796-ae4f-4c98-8f2d-4b147e0323f6

(Invited, Digital Presentation) Tuning the Electrodeposition of Actinides in Molten Alkali Halide Salts

Autor: Molly M MacInnes, Kristen A Pace, Ida M DiMucci, Nickolas H Anderson, Benjamin W Stein, Stosh Kozimor, Francisca R Rocha, Zachary R Jones, Veronika Mocko, Enrique R Batista, Cecilia Eiroa-Lledo, Maksim Y Livshits, Jennifer N Wacker, Karah E Knope, Ping Yang

Publikováno v: ECS Meeting Abstracts. :1196-1196

Molten salts have found use as solvents in numerous applications including nuclear reactors, batteries, and the extraction and purification of various metals. Unfortunately, understanding of the chemistry of molten salt solutions is limited. In this

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2ba826dd66052118c7824750af4ef13c
https://doi.org/10.1149/ma2022-01231196mtgabs

Investigation of Nitrile Hydration Chemistry by Two Transition Metal Hydroxide Complexes: Mn–OH and Ni–OH Nitrile Insertion Chemistry

Autor: James M. Boncella, Nickolas H. Anderson, Aaron M. Tondreau

Publikováno v: Organometallics. 37:4675-4684

Herein we describe the synthesis of a series of nickel complexes, including the formation of [(iPrPNHP)Ni(PMe3)][BPh4] (iPrPNHP = HN(CH2CH2(PiPr2))2). The ability of this phosphine complex to perform the 1,2-addition of H2O to produce the Ni–OH spe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9ac907852b27d5bd44c06837c20cc329
https://doi.org/10.1021/acs.organomet.8b00687