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pro vyhledávání: '"Nicholas R. Wiedmaier"'
Publikováno v:
Dalton Transactions. 50:11814-11820
The ruthenium carbene pincer complex 2 was synthesized treating the benzo annulated cycloheptatriene bisphosphine 1 with RuCl3. Addition of three equivalents of hydrogen to the carbocyclic carbene complex 2 was achieved in reaction of 2 with hydrogen
Autor:
Georg Leistikow, Klaus Eichele, Hansjörg Speth, Hermann A. Mayer, Hartmut Schubert, Lars Wesemann, Nicholas R. Wiedmaier
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(21)
The benzo annulated cycloheptatriene PCP pincer ruthenium hydrido dicarbonyl complex syn-2 was prepared in one step by treatment of the ligand 1 with Ru3(CO)12. Protonation of syn-2 with the superacid [H(Et2O)2][BArF24] {[BArF24]− = tetrakis[bis(tr