Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Nicholas D, Kennedy"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 4, Pp 547-551 (2020)
The title compounds, [Mo(C5H5)(COCH3)(C6H12N3P)(CO)2], (1), and [Mo(C5H5)(COCH3)(C9H16N3O2P)(C6H5)2))(CO)2], (2), have been prepared by phosphine-induced migratory insertion from [Mo(C5H5)(CO)3(CH3)]. The molecular structures of these complexes are q
Externí odkaz:
https://doaj.org/article/f6fcb93c7d5e45519a37af2fd788a2cc
Autor:
Hannah H. Mallard, Nicholas D. Kennedy, Nathan A. Rudman, Alexa M. Greenwood, Jonathan Nicoleau, Corey E. Angle, Nicole A. Torquato, Michael R. Gau, Patrick J. Carroll, Mitchell R. Anstey
Publikováno v:
IUCrData, Vol 5, Iss 9, p x201248 (2020)
In the title compound, C40H36B2N4O5, the B—O—B bond angle is 132.75 (13) and the dihedral angle between the benzodiazborole rings is 73.02 (5)°. In the crystal, weak C—H...O interactions link the molecules.
Externí odkaz:
https://doaj.org/article/750cfc246cd047e9a2e3a833424cfb04
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 4, Pp 547-551 (2020)
The title compounds, [Mo(C5H5)(COCH3)(C6H12N3P)(CO)2], (1), and [Mo(C5H5)(COCH3)(C9H16N3O2P)(C6H5)2))(CO)2], (2), have been prepared by phosphine-induced migratory insertion from [Mo(C5H5)(CO)3(CH3)]. The molecular structures of these complexes are q
Autor:
Corey E. Angle, Alexa M. Greenwood, Mitchell R. Anstey, Nicholas D. Kennedy, Micheal R. Gau, Patrick J. Carroll, Nicole A. Torquato, Jonathan Nicoleau, Hannah H. Mallard, Nathan A. Rudman
Publikováno v:
IUCrData, Vol 5, Iss 9, p x201248 (2020)
In the title compound, C40H36B2N4O5, the B—O—B bond angle is 132.75 (13) and the dihedral angle between the benzodiazborole rings is 73.02 (5)°. In the crystal, weak C—H...O interactions link the molecules.
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
Solid-state structures of the title compounds are presented to show the relative effects of 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) ligands on the molecular and extended str