Zobrazeno 1 - 10
of 57
pro vyhledávání: '"Neopentyl alcohol"'
Autor:
Hideo Togo, Masatoshi Ezawa
Publikováno v:
European Journal of Organic Chemistry. 2017:2379-2384
A one-pot protocol to obtain C1-homologated aliphatic nitriles was achieved by treating aromatic and aliphatic aldehydes with the (methoxymethyl)triphenylphosphonium ylide followed by hydrolysis of the resulting methyl vinyl ethers with pTsOH (Ts = p
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Autor:
A. P. Zeelenberg
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 81:720-728
The slow oxidation of neopentane has been investigated in a static system at 260°. Analysis by means of gas-liquid chromatography (GLC) during the early stages of the combustion showed the presence of isobutene, acetone, isobutyraldehyde, pivalaldeh
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 103:453-461
Primary hydroxy groups as in neopentyl alcohol 7 or neopentylglycol 18 react readily with perfluorobutanesulfonyl fluoride 1 in the presence of 2 equiv. of the nucleophilic 4-dialkylaminopyridines 4 to afford high yields of the corresponding N-alkyl-
Autor:
Yu Lu, Michael J. Krische
Publikováno v:
Organic Letters. 11:3108-3111
Under the conditions of C-C bond forming transfer hydrogenation, 1,3-propanediol 1 engages in double asymmetric carbonyl allylation to furnish the C(2)-symmetric diol 2. Double ozonolysis of 2 followed by TBS protection delivers aldehyde 3, which is
Publikováno v:
International Journal of Mass Spectrometry. 278:26-31
The dissociation dynamics of energy-selected neopentylamine cations, (CH3)3CCH2NH2+, were studied using threshold photoelectron photoion coincidence (TPEPICO) spectroscopy in which ion time-of-flight (TOF) distributions are recorded as a function of
Publikováno v:
Journal of Computational Chemistry. 28:1561-1571
The neopentyl and the pinacol rearrangements as examples of Wagner-Meerwein rearrangements were investigated by the use of DFT calculations. As the first reaction, a model of neopentyl chloride (1b) and (H2O)12 was employed. In the reaction, the patt
Publikováno v:
Catalysis Communications. 3:25-28
Metal triflates such as Sn(Otf) 2 and La(Otf) 3 act as efficient catalysts for cleaving 2,4,4,-trimethyl-pentane-2-hydroperoxide into neopentyl alcohol and acetone in sulpholane. Compared to H 2 SO 4 , the conventional catalyst for hydroperoxide rear
Publikováno v:
Journal of computational chemistry. 35(30)
B3LYP calculations were carried out on hydrolysis reactions of monosubstituted(R) phosphate dianion and sulfate monoanion. In the reacting system, water clusters (H2O)22 and (H2O)35 are included to trace reaction paths. For both P and S substrates wi
Publikováno v:
Journal of the American Oil Chemists' Society. 78:219-223
Oleic acid (cis-9-octadecenoic acid) was converted in excellent yield to the estolide, which was then esterified with 2,2-dimethypropan-1-ol (neopentyl alcohol), cis-9-octadence-1-ol (oleyl alcohol), and 2-propanol to generate the corresponding estol