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of 6
pro vyhledávání: '"Neil W. J. Scott"'
Publikováno v:
ACS Catalysis. 12:11615-11638
Autor:
Sam Hart, Simon B. Duckett, Ian J. S. Fairlamb, Adrian C. Whitwood, Evans Dzotsi, Neda Jeddi, Neil W. J. Scott, Guan Dexin, Natalie E. Pridmore, Kate M. Appleby
Publikováno v:
Organometallics. 40:3560-3570
Tripalladium clusters of the type [Pd3(PPh3)4]2+, wherein three linearly connected Pd atoms are stabilized by phosphine and arsine ligands, have been detected and isolated as intermediates during the reduction of well-defined mononuclear [Pd(OTf)2(XP
Publikováno v:
Organometallics
[PdI2(μ-PPh2)(μ2-OAc)(PPh3)2] is the reduction product of PdII(OAc)2(PPh3)2, generated by reaction of 'Pd(OAc)2' with two equivalents of PPh3. Here, we report that the reaction of [PdI2(μ-PPh2)(μ2-OAc)(PPh3)2] with PPh3 results in a nuanced dispr
Autor:
Mark James Ford, Neil W. J. Scott, Charlotte E. Willans, Theo Tanner, Ian J. S. Fairlamb, Adrian C. Whitwood, Neda Jeddi, Anthony Eyles, Lauriane Simon
Publikováno v:
Journal of the American Chemical Society
Site-selective dihalogenated heteroarene cross-coupling with organometallic reagents usually occurs at the halogen proximal to the heteroatom, enabled by intrinsic relative electrophilicity, particularly in strongly polarized systems. An archetypical
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::960e7d81af41cddf76b8a595e3a9fdf1
https://eprints.whiterose.ac.uk/175489/6/jacs.1c05294.pdf
https://eprints.whiterose.ac.uk/175489/6/jacs.1c05294.pdf
Autor:
Neil W. J. Scott, Rachel R. Parker, Adrian C. Whitwood, Ian J. S. Fairlamb, Mark James Ford, Christoph Schotes
Publikováno v:
Chemical Science. 10:7898-7906
Palladium(II) acetate ‘Pd(OAc)2’/nPPh3 is a ubiquitous precatalyst system for cross-coupling reactions. It is widely accepted that reduction of in situ generated trans-[Pd(OAc)2(PPh3)2] affords [Pd0(PPh3)n] and/or [Pd0(PPh3)2(OAc)]− species whi
Autor:
Ian J. S. Fairlamb, Neil W. J. Scott
Publikováno v:
Nanoparticles in Catalysis ISBN: 9783030566296
This chapter reviews the state of the art in the use of nanoparticles in cross-coupling catalysis, with a focus on C—H activation chemistry. Current understanding of the mechanistic role of heterogeneous catalyst sources as applied to classic cross
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::07135639efa73951cb852ebccf417f76
https://doi.org/10.1007/3418_2020_41
https://doi.org/10.1007/3418_2020_41