Zobrazeno 1 - 10
of 49
pro vyhledávání: '"Neil J. Brown"'
Autor:
Milo S. P. Shaffer, Neil J. Brown, Matthew Allinson, Jonathan Weiner, Peter P. Wells, Klaus Hellgardt, Emma K. Gibson, Andrés García-Trenco, Edward R. White, Yuxin Chen, Charlotte K. Williams
Publikováno v:
ACS Catalysis. 5:2895-2902
A series of zinc oxide and copper(0) colloidal nanocatalysts, produced by a one-pot synthesis, are shown to catalyze the hydrogenation of carbon dioxide to methanol. The catalysts are produced by the reaction between diethyl zinc and bis(carboxylato/
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0ef71285996911ab2f10582407f9a52d
https://doi.org/10.1021/cs502038y
https://doi.org/10.1021/cs502038y
Autor:
Mark W. Whiteley, Kathryn A.E. Roberts, Neil J. Brown, Paul J. Low, Hannah N. Roberts, Joseph J. W. McDouall
Publikováno v:
Polyhedron. 86:89-97
DFT calculations at the B3LYP/Def2-SVP level have been conducted on the half-sandwich cycloheptatrienyl molybdenum complexes [Mo(CO)(3)(eta-C7H7)(+), [1](+) and [MoBrL2(eta-C7H7)](n+) (L-2= 2 CO, n = 0, 2; L-2= bpy, n = 0, 3; L-2 = bpy, n = 1, [3](+)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4659de42cec165e735da17b9c5c7e5c2
https://doi.org/10.1016/j.poly.2014.05.027
https://doi.org/10.1016/j.poly.2014.05.027
Publikováno v:
Inorganic Chemistry. 53:3742-3752
The reactivity of the novel tridentate phosphine ligand N(CH2PCyp2)3 (N-triphos(Cyp), 2; Cyp = cyclopentyl) with various ruthenium complexes was investigated and compared that of to the less sterically bulky and less electron donating phenyl derivati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d9fd7a60410869a4ec61dc64b6991e29
https://doi.org/10.1021/ic500030k
https://doi.org/10.1021/ic500030k
Autor:
Milo S. P. Shaffer, Sergei G. Kazarian, Charlotte K. Williams, Colin W. Keyworth, Klaus Hellgardt, Ian P. Silverwood, Neil J. Brown, Geoff Kelsall
Publikováno v:
Applied Spectroscopy. 68:88-94
Attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy has been applied in situ to study gas adsorption on a colloidal stearate-capped zinc oxide (ZnO) surface. Infrared spectra of a colloidal stearate-capped ZnO catalyst sub
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de947b382ff0151a5427243508164063
https://doi.org/10.1366/13-07174
https://doi.org/10.1366/13-07174
Autor:
David Collison, Ruth Edge, Hannah N. Roberts, Neil J. Brown, Emma C. Fitzgerald, Mark W. Whiteley, Yien T. Ta, Paul J. Low
Publikováno v:
Organometallics. 31:6322-6335
Two series of extended carbon chain butadiynyl and hexatriynyl complexes, [Mo{(C≡C)nC≡CSiMe3}(bpy)(η-C7H7)] (n = 1, 2; bpy = 2,2′-bipyridine) and [Mo{(C≡C)nC≡CR}(dppe)(η-C7H7)] (n = 1, R = H, SiMe3; n = 2, R = SiMe3; dppe = Ph2PCH2CH2PPh2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::653eb616eee836f319737897b59afdcb
https://doi.org/10.1021/om3005756
https://doi.org/10.1021/om3005756
Autor:
Neil J. Brown, Mark W. Whiteley, Floriana Tuna, Andrew Beeby, Paul J. Low, David Collison, Emma C. Fitzgerald, Madeleine Helliwell, Ruth Edge, Hannah N. Roberts
Publikováno v:
Organometallics. 31:157-169
The cycloheptatrienyl molybdenum alkynyl complex [Mo(C≡CH)(dppe)(η-C7H7)], 1 (dppe = Ph2PCH2CH2PPh2), undergoes oxidative dimerization on reaction with [FeCp2]PF6 in thf at −78 °C to give the bis(vinylidene) [{Mo(dppe)(η-C7H7)}2(μ-C═CH-CH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5e313c8bbe321337abfb4012840875c3
https://doi.org/10.1021/om200712m
https://doi.org/10.1021/om200712m
Autor:
Mark W. Whiteley, Paul J. Low, Ross Lewin, David Collison, Neil J. Brown, Ruth Edge, Hannah N. Roberts
Publikováno v:
Organometallics. 30:3763-3778
Two series of bis-phosphine-substituted cyclopentadienyl molybdenum alkynyl complexes, [Mo(C≡CR)(CO)(dppe)Cp′] and trans-[Mo(C≡CR)(CO)(PMe3)2Cp′] (R = Ph or C6H4-4-Me, dppe = Ph2PCH2CH2PPh2, Cp′ = Cp or Cp*), have been prepared and structur
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::60c4afe59ac5d7cfecfa260e6d3b370a
https://doi.org/10.1021/om200229c
https://doi.org/10.1021/om200229c
Autor:
Paul J. Low, Neil J. Brown, Wing Y. Man, Judith A. K. Howard, Sheng Hua Liu, Julian D. Farmer, Dmitry S. Yufit, Jianlong Xia
Publikováno v:
Organometallics. 30:1852-1858
A combination of IR spectroelectrochemistry and DFT calculations has been used to demonstrate that the vinyl ligands in the complexes [Ru(CH═CHC6H4Me-4)Cl(CO)(PMe3)3] and [{RuCl(CO)(PMe3)3}2(μ-CH═CHC6H4CH═CH)] are redox noninnocent, and one-el
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::48bca1c063516aae3c9143b352093c95
https://doi.org/10.1021/om1010534
https://doi.org/10.1021/om1010534
Autor:
Laura Carthy, Hannah N. Lancashire, Mark W. Whiteley, Emma C. Fitzgerald, Mark A. Holden, Madeleine Helliwell, David Collison, Neil J. Brown, Paul J. Low, Joseph J. W. McDouall, Ruth Edge
Publikováno v:
Dalton Trans.. 40:1267-1278
The first examples of vinylidene complexes of the cycloheptatrienyl tungsten system [W(C=CHR)(dppe)(η-C₇H₇)](+) (dppe = Ph₂PCH₂CH₂PPh₂; R = H, 3; Ph, 4; C₆H₄-4-Me, 5) have been synthesised by reaction of [WBr(dppe)(η-C₇H₇)], 1,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::be818465ed0bb2dacf0d391b7266538d
https://doi.org/10.1039/c0dt01150a
https://doi.org/10.1039/c0dt01150a
Autor:
Mark W. Whiteley, Mark A. Fox, Neil J. Brown, Hannah N. Lancashire, Dmitry S. Yufit, Ruth Edge, David Collison, Paul J. Low, Judith A. K. Howard
Publikováno v:
Organometallics. 30:884-894
The design and study of organometallic mixed-valence complexes is complicated by the mixing of metal d and bridging ligand π orbitals, which often makes the assignment of metal oxidation states amb...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bde8666f305ab81cd79db7056914eb99
https://doi.org/10.1021/om1010353
https://doi.org/10.1021/om1010353