Zobrazeno 1 - 10
of 486
pro vyhledávání: '"Neil G. Connelly"'
Autor:
Elena Patron, Neil G. Connelly, Christopher J. Adams, Kirsty M. Anderson, Philip H. Rieger, A. Guy Orpen, Owen D. Hayward, David J. Harding
Publikováno v:
Dalton Trans.. :530-543
The d4 halide complexes [MX(CO)(η-RCCR)Tp′] {R = Me, M = W, X = F; R = Ph, M = Mo or W, X = F or Cl; Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate} undergo two-electron oxidation in the presence of a halide source to give the d2 monocations [MX1X
Autor:
Christopher J. Adams, Neil G. Connelly, Martin R. Gill, A. Kantacha, J. P. H. Charmant, A. G. Orpen, S. Onganusorn
Publikováno v:
Dalton Trans.. :2283-2294
The salts [NEt4][Ru(CN)(CO)2L(o-O2C6Cl4)] {L=PPh3 or P(OPh)3}, which undergo one-electron oxidation at the catecholate ligand to give neutral semiquinone complexes [Ru(CN)(CO)2L(o-O2C6Cl4)], react with the dimers [{Ru(CO)2L(micro-o-O2C6Cl4)}2] {L=PPh
Autor:
Philip H. Rieger, Elena Patron, A. Guy Orpen, Ian M. Bartlett, Neil G. Connelly, Christopher J. Adams, Susannah Carlton, Owen D. Hayward, Christopher D. Ray, David J. Harding
Publikováno v:
Dalton Trans.. :62-72
The d4 halide complexes [MX(CO)(η-RCCR)Tp′] {X = F, Cl, Br or I; R = Me or Ph; M = Mo or W; Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate} undergo one-electron oxidation to the d3 monocations [MX(CO)(η-RCCR)Tp′]+, isolable for M = W, R = Me. X
Autor:
Philip H. Rieger, Eric J. L. McInnes, Ian M. Bartlett, Neil G. Connelly, Christopher J. Adams, A. Guy Orpen, Supakorn Boonyuen, David J. Harding, Owen D. Hayward, Michael J. Quayle
Publikováno v:
Dalton Trans.. :3466-3477
Reduction of [M(CO)2(η-RCCR′)Tp′]X {Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate, M = Mo, X = [PF6]−, R = R′ = Ph, C6H4OMe-4 or Me; R = Ph, R′ = H; M = W, X = [BF4]−, R = R′ = Ph or Me; R = Ph, R′ = H} with [Co(η-C5H5)2] gave para
Autor:
Juan Cámpora, Diego del Río, Neil G. Connelly, Eleuterio Álvarez, Jorge A. López, Pilar Palma
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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5 páginas, 2 figuras, 2 tablas, esquemas.
A new method for the synthesis of cationic Pd(IV) complexes, based on the chemical oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is presented. Electrochemical anal
A new method for the synthesis of cationic Pd(IV) complexes, based on the chemical oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is presented. Electrochemical anal
Autor:
Celedonio M. Alvarez, M. Esther García, M. Teresa Rueda, Miguel A. Ruiz, David Sáez, Neil G. Connelly
Publikováno v:
Organometallics. 24:650-658
Reaction of the hydride complexes [M 2 Cp 2 (μ-H)(μ-PPh 2 )(CO) 4 ] (M = Mo, W; Cp = η 5 -C 5 H 5 ) with [FeCp 2 ]BF 4 proceeds in a 1:2 ratio to give the unsaturated tetracarbonyl salts [M 2 Cp 2 -(μ-PPh 2 )(CO) 4 ]BF 4 , which spontaneously (M
Publikováno v:
Organometallics. 23:4750-4758
The complex trans-[Fe2Cp2(μ-H)(μ-PPh2)(CO)2] is obtained in 91% yield by refluxing toluene solutions of [Fe2Cp2(CO)4] (Cp = η5-C5H5) and the secondary phosphine PPh2H. This compound isomerizes upon irradiation with visible−UV light under a CO at
Autor:
Jason A. Halfen, Lucía Riera, Victor Riera, Neil G. Connelly, Supakorn Boonyuen, Dolores Morales, Daniel Miguel, Luciano Cuesta, Julio Pérez, Laurent Coue
Publikováno v:
Chemistry - A European Journal. 10:1906-1912
The reaction of the complex [Mo(OTf)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (OTf = trifluoromethylsulfonate; phen = 1,10-phenanthroline) with tetrabutylammonium fluoride trihydrate afforded the fluoride complex [MoF(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen
Autor:
Manuel Bardaji, A. Guy Orpen, Neil G. Connelly, Christopher J. Adams, Kirsty M. Anderson, Philip H. Rieger, Nicholas J. Goodwin, Estefania Llamas-Rey
Publikováno v:
Dalton Trans.. :683-694
Cationic nitrile complexes and neutral halide and cyanide complexes, with the general formula [MnL1L2(NO)(eta-C5H4Me)]z, undergo one-electron oxidation at a Pt electrode in CH2Cl2. Linear plots of oxidation potential, Eo', vs. nu(NO) or the Lever par
Autor:
Mathivathani Kandiah, A. Guy Orpen, Christopher J. Adams, Kirsty M. Anderson, Neil G. Connelly, R. Angharad Baber
Publikováno v:
Dalton Trans.. :3353-3359
The nominally square-planar coordination of the d8 complexes [MClL1L2(p-XC6H4NNNHC6H4X-p)] (M = Rh, L1 = L2 = CO, X = H, Me, Et or F; M = Ir, L1 = L2 = CO, X = Me; M = Pd or Pt, L1 = Cl, L2 = PPh3, X = Me; M = Pd, L1L2 = η3-C3H5, X = Me), with the t