Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride

Autor: Neelakandan Devika, Nandhagopal Raja, Subbiah Ananthalakshmi, Bruno Therrien

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 3, Pp 248-250 (2015)

The cation of the title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinylidenepyridine ligand is non-planar, an angle

Externí odkaz: https://doaj.org/article/5cdd99962dc44bca806cd9d8bdf2f8bf

Amidation of aldehydes using mono-cationic half-sandwich rhodium(III) complexes with functionalized phenylhydrazone ligands

Autor: Neelakandan Devika, Subbiah Ananthalakshmi, Gajendra Gupta, Bruno Therrien, Nandhagopal Raja

Publikováno v: Journal of Organometallic Chemistry. 886:65-70

A series of mono-cationic half-sandwich rhodium(III) complexes have been synthesized in methanol using phenylhydrazone-derived ligands (L1–L6) and the starting precursor [(η5-C5Me5)2Rh2(μ-Cl)2Cl2] in a 2:1 molar ratio. The N,N′-phenylhydrazone

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4cc7c69808993c5773251e8786ee2add
https://doi.org/10.1016/j.jorganchem.2019.02.018

Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride

Autor: Subbiah Ananthalakshmi, Nandhagopal Raja, Neelakandan Devika, Bruno Therrien

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 3, Pp 248-250 (2015)
Acta Crystallographica Section E: Crystallographic Communications

The title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::be0bc72091ed53dd031110d602fc17a3
http://scripts.iucr.org/cgi-bin/paper?S205698901500184X