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pro vyhledávání: '"Navin R. Yadav"'
Publikováno v:
New Journal of Chemistry. 46:582-591
The reaction between aryl olefins and thiols in the presence of Oxone in toluene-water (9:1, v/v) affords β-hydroxy-2-arylethyl aryl sulfides smoothly by interception of the intermediary thiyl radicals with aryl olefins; the former are generated by
Thiosulfonates are accessed by oxidation of feed-stock thiols using either DMP in DCM or IBX in MeCN at rt (~30 degree C). The protocol gives access to a variety of thiosulfonates in good to excellent yields from both aromatic and aliphatic thiols. T
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::89bc46a7c7d1325b94838e23115f3330
https://doi.org/10.26434/chemrxiv-2023-q24pc
https://doi.org/10.26434/chemrxiv-2023-q24pc
Publikováno v:
Tetrahedron. 75:2169-2174
A facile one-pot access to a broad range of isatins by direct oxidation of indoles using NIS/IBX reagent in DMSO at 25 °C in very good isolated yields is reported. It is shown by mechanistic investigations that a number of substituted indoles react