Zobrazeno 1 - 5
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pro vyhledávání: '"Nathan Z. Barefoot"'
Autor:
Omar W. Steward, Robert J. Mycka, William T. Eckenhoff, Nathan Z. Barefoot, Fraser F. Fleming
Publikováno v:
Tetrahedron. 69:366-376
Deprotonating γ- and δ-hydroxynitriles with i-PrMgCl allows highly diastereoselective alkylations controlled by the asymmetry of the remote carbinol stereocenter. Mechanistic experiments are consistent with γ-hydroxynitriles alkylating via a chela
Publikováno v:
Journal of the American Society for Mass Spectrometry. 23:282-289
A comparison between solution and gas phase modification of primary amine sites in model peptide cations with N-hydroxysuccinimide (NHS) ester reagents is presented. In all peptides, the site of modification in solution was directed to the N-terminus
N-hydroxysuccinimide (NHS) esters have been used for gas-phase conjugation reactions with peptides at nucleophilic sites, such as primary amines (N-terminus, ε-amine of lysine) or guanidines, by forming amide bonds through a nucleophilic attack on t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b375ed70b377abd291de881423e39720
https://europepmc.org/articles/PMC4654944/
https://europepmc.org/articles/PMC4654944/
ChemInform Abstract: γ- and δ-Hydroxynitriles: Diastereoselective Electrophile-Dependent Alkylations
Autor:
Omar W. Steward, Nathan Z. Barefoot, Robert J. Mycka, Fraser F. Fleming, William T. Eckenhoff
Publikováno v:
ChemInform. 44
Deprotonating γ- and δ-hydroxynitriles with i-PrMgCl allows highly diastereoselective alkylations controlled by the asymmetry of the remote carbinol stereocenter. Mechanistic experiments are consistent with γ-hydroxynitriles alkylating via a chela
Publikováno v:
Physical chemistry chemical physics : PCCP. 12(29)
Rotational spectra of p-, m-, and o-cyanophenol have been measured in the range of 10.5-21 GHz and fit using Watson's A-reduction Hamiltonian coupled with nuclear quadrupole coupling interaction terms for the (14)N nuclei. Ab initio calculations at t