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of 11
pro vyhledávání: '"Natalja Früh"'
Autor:
Antonio Togni, Natalja Früh
Publikováno v:
Angewandte Chemie. 126:10989-10992
Die direkte elektrophile Trifluormethylierung von Silylketeniminen (SKIs) mit hypervalenten Iodreagentien fuhrt zur Bildung von quartaren α-Trifluormethylnitrilen in guter Ausbeute. Diese neue Reaktion wurde mit einer Auswahl substituierter SKIs unt
Publikováno v:
Angewandte Chemie International Edition. 52:7724-7727
Chiral-anion phase-transfer catalysis (PTC) has been applied towards the enantioselective fluorocyclization reactions of 1,3-dienes. The method affords unprecedented fluorinated benz[f]isoquinoline and octahydroisoquinoline products in high yields an
Publikováno v:
Organic letters. 18(4)
A copper-catalyzed fluoroalkylation–cyclization sequence of alkenes and alkynes enables the synthesis of fluorinated tetra- and dihydroimidazopyridines in moderate to excellent yields within 1 h at 70 °C. This reaction, which is carried out using
Publikováno v:
Angewandte Chemie. 124:6617-6621
Publikováno v:
Angew. Chem. Int. Ed.
Effective CF(3) transfer: Various electron-rich nitrogen heterocycles (pyrazoles, triazoles, and tetrazoles) can be directly N-trifluoromethylated by a hypervalent iodine reagent in an efficient manner. The optimized procedure, which includes an in s
Autor:
Ekaterina V. Vinogradova, Katrin Niedermann, Antonio Togni, Matthias S. Wiehn, Aitor Moreno, Natalja Früh
Publikováno v:
Angewandte Chemie. 123:1091-1095
Publikováno v:
Topics in current chemistry. 373
This chapter describes synthesis, structural properties, activation modes, and applications of hypervalent iodine reagents for trifluoromethylation, thereby focusing on recent advances.
Publikováno v:
ChemInform. 46
Publikováno v:
Chemical Reviews, 115 (2)
Chem. Rev.
Chem. Rev.
Chemical Reviews, 115 (2)
ISSN:0009-2665
ISSN:1520-6890
ISSN:0009-2665
ISSN:1520-6890
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cef34fea456735be9e571bcc0de78089
https://hdl.handle.net/20.500.11850/99433
https://hdl.handle.net/20.500.11850/99433
Autor:
Antonio Togni, Natalja Früh
Publikováno v:
Angewandte Chemie (International ed. in English). 53(40)
The direct electrophilic trifluoromethylation of silyl ketene imines (SKIs) with hypervalent iodine reagents leads to the formation of quaternary α-trifluoromethyl nitriles in good yields. This new reaction has been carried out with a variety of sub