Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Natalie L. Cromhout"'
Autor:
C. John McAdam, Anthony J. Palmer, Jim Simpson, Natalie L. Cromhout, Brian H. Robinson, Anthony R. Manning
Publikováno v:
Inorganica Chimica Acta. 354:54-60
[Co3(η5-C5H5)3(μ3-S)(μ3-CSR)][I], [5]I (R=Me), [6]I (R=Et) are not dealkylated by treatment with [PhCH2NMe3]OH, NaOH, NaOMe or NaOEt in either CH2Cl2 or MeOH–EtOH solutions. [{Co(η5-C5H5)}2{Fe(CO)2(PPh3)}(μ3-S)(μ3-CSMe)][X], [3]X (X−=I− o
Autor:
Natalie L. Cromhout, Donagh Courtney, John F. Gallagher, Anthony R. Manning, Desmond Cunningham, Patrick McArdle, S.I Pratt
Publikováno v:
Inorganica Chimica Acta. 327:98-107
The iron hydrido complex HFe(CO)2{P(OPh)3}{(PhO)2POC6H4} (1), was rapidly deprotonated by DBU or [BzMe3N][OH] in THF to afford the new carbonyl iron anion [Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}]− ([2]−), containing an ortho-metallated triphenyl phosphit
Autor:
Natalie L. Cromhout, Alan T. Hutton
Publikováno v:
Journal of Coordination Chemistry. 52:169-183
The synthesis and characterization of a new series of 4-(4′ -n-alkoxybiphenyl)mercury(II) dithizonates, [C n H2n + 1OC6H4C6H4Hg(Hdptc)] (H2dptc = 1,5-diphenylthiocarbazone = dithizone; n = 4, 5, 10, 14 or 18), is described. Meticulous attention to
Publikováno v:
Journal of Organometallic Chemistry. 612:61-68
UV-irradiation of Fe(CO) 3 {P(OPh) 3 } 2 ( 1 ) afforded an orthometallated iron hydride HFe(CO) 2 {P(OPh) 3 }{(PhO) 2 POC 6 H 4 } ( 2 ) which was reacted in situ with alkynes R 1 CCR 2 . Internal alkynes reacted to give either η 2 -alkyne Fe(CO)
Autor:
Natalie L. Cromhout, Alan T. Hutton
Publikováno v:
Applied Organometallic Chemistry. 14:66-74
The synthesis and characterization of a seriesof 4 - (4′- n -alkoxybenzylideneimino)phenyl-mercury (II) dithizonates, [CnH2n+1OC6H4CHNC6H4Hg (Hdptc)] (H2dptc = 1,5-diphenylthiocarbazone = dithizone; n = 1, 4, 12, 14 or 18), is described. The
Autor:
Patrick McArdle, J. Renze, M. Barrow, Desmond Cunningham, Anthony R. Manning, Natalie L. Cromhout
Publikováno v:
Journal of Organometallic Chemistry. 563:201-207
The reaction of Fe(CO)2(η2-CS2){P(OPh)3}2 1 with two equivalents of PBu3 in a minimum volume of a polar solvent such as acetonitrile or dimethylsulfoxide afforded the thiocarbonyl derivative Fe(CO)2(CS){P(OPh)3}2 2 in ca. 80% yield whereas reaction
Autor:
and Andrew E. H. Wheatley, Paul R. Raithby, Alexander Steiner, Christopher A. Russell, Christopher N. Harmer, Natalie L. Cromhout, David R. Armstrong, David Moncrieff, Michael A. Beswick, Dominic S. Wright
Publikováno v:
Organometallics. 17:3176-3181
The coordination of [(η-Cp)2Pb] and [(η-Cp)2Sn] by bidentate Lewis-base ligands gives the first examples of adducts of neutral p-block metallocenes. Ab initio MO calculations of [(η-Cp)2Pb·TMEDA] (1) (TMEDA = (Me2NCH2)2), [Cp2Pb·4,4‘-Me2bipy]
Publikováno v:
Polyhedron. 16:4257-4264
Reaction of potassium 3{5}-(3′,4′-dimethoxyphenyl)pyrazolide with 2-bromopyridine in diglyme at 130°C for 3 days followed by an aqueous quench, affords 1-{pyrid-2-yl}-3-{3′,4′-dimethoxyphenyl}pyrazole (L2) in 69% yield after recrystallizatio
Autor:
Dominic S. Wright, Natalie L. Cromhout, Christopher N. Harmer, Moira-Ann Rennie, Michael A. Paver, Michael A. Beswick, and Alexander Steiner, Paul R. Raithby
Publikováno v:
Inorganic Chemistry. 36:1740-1744
Transmetalation reactions of the polyimido Sb(III) anions [Sb(3)(NCy)(4)(HNCy)(2)](-), [Sb(2)(NCy)(4)](2)(-), and [Sb(NCy)(3)](3)(-) with metal sources allows the logical assembly of cage compounds containing various mixed-metal stoichiometries. The
Publikováno v:
Inorganic Chemistry Communications. 2:389-391
The ionic coupling of the carbonyl cluster anion [Os3Co(CO)13]− (1) with [Ru(η5-C5H5)(NCMe)3]+ affords the new pentanuclear triheterometallic cluster Os3CoRu(CO)13(η5-C5H5) (2) as well as the known bimetallic cluster compounds HOs3Ru(CO)11(η5-C5