Zobrazeno 1 - 10
of 155
pro vyhledávání: '"Natalia V. Belkova"'
Autor:
Alexander G. Medvedev, Pavel A. Egorov, Alexey A. Mikhaylov, Evgeny S. Belyaev, Gayane A. Kirakosyan, Yulia G. Gorbunova, Oleg A. Filippov, Natalia V. Belkova, Elena S. Shubina, Maria N. Brekhovskikh, Anna A. Kirsanova, Maria V. Babak, Ovadia Lev, Petr V. Prikhodchenko
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-8 (2024)
Abstract Despite the significance of H2O2-metal adducts in catalysis, materials science and biotechnology, the nature of the interactions between H2O2 and metal cations remains elusive and debatable. This is primarily due to the extremely weak coordi
Externí odkaz:
https://doaj.org/article/c2058cd1be3f43a18b30d70a286512bb
Autor:
Vladislava A. Kirkina, Vasilisa A. Kulikova, Evgenii I. Gutsul, Zufar N. Gafurov, Ilias F. Sakhapov, Dmitry G. Yakhvarov, Yulia V. Nelyubina, Oleg A. Filippov, Elena S. Shubina, Natalia V. Belkova
Publikováno v:
Inorganics, Vol 11, Iss 5, p 212 (2023)
The interaction between (PNP)PdH (1); PNP = bis(2-diisopropylphosphino-4-methylphenyl)amide and different acids (CF3SO3H, HBF4∙Et2O, fluorinated alcohols and formic acid) was studied in benzene or toluene as well as in neat alcohols by IR and NMR s
Externí odkaz:
https://doaj.org/article/4a775419632b4c92ac517ae3338dd4d5
The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
Autor:
Elena S. Osipova, Sergey A. Kovalenko, Ekaterina S. Gulyaeva, Nikolay V. Kireev, Alexander A. Pavlov, Oleg A. Filippov, Anastasia A. Danshina, Dmitry A. Valyaev, Yves Canac, Elena S. Shubina, Natalia V. Belkova
Publikováno v:
Molecules, Vol 28, Iss 8, p 3368 (2023)
Acid-base characteristics (acidity, pKa, and hydricity, ΔG°H− or kH−) of metal hydride complexes could be a helpful value for forecasting their activity in various catalytic reactions. Polarity of the M–H bond may change radically at the stag
Externí odkaz:
https://doaj.org/article/e9243d1afd10415b9193ede303ec0ee6
Publikováno v:
Molecules, Vol 26, Iss 12, p 3754 (2021)
The mechanism of the consecutive halogenation of the tetrahydroborate anion [BH4]− by hydrogen halides (HX, X = F, Cl, Br) and hexahydro-closo-hexaborate dianion [B6H6]2− by HCl via electrophile-induced nucleophilic substitution (EINS) was establ
Externí odkaz:
https://doaj.org/article/c1532541251b495f83c0be38229595da
Autor:
Igor E. Golub, Oleg A. Filippov, Vasilisa A. Kulikova, Natalia V. Belkova, Lina M. Epstein, Elena S. Shubina
Publikováno v:
Molecules, Vol 25, Iss 12, p 2920 (2020)
Thermodynamic hydricity (HDAMeCN) determined as Gibbs free energy (ΔG°[H]−) of the H− detachment reaction in acetonitrile (MeCN) was assessed for 144 small borane clusters (up to 5 boron atoms), polyhedral closo-boranes dianions [BnHn]2−, and
Externí odkaz:
https://doaj.org/article/f2175fb15866462a88c5122879b16798
Autor:
Sergey V. Safronov, Elena S. Osipova, Yulia V. Nelyubina, Oleg A. Filippov, Irina G. Barakovskaya, Natalia V. Belkova, Elena S. Shubina
Publikováno v:
Molecules, Vol 25, Iss 9, p 2236 (2020)
Ruthenocene-based PCPtBu pincer ligands were used to synthesize novel pincer palladium chloride RcF[PCPtBu]PdCl (2a) and two novel palladium tetrahydroborates RcF[PCPtBu]Pd(BH4) (3a) and Rc*[PCPtBu]Pd(BH4) (3b), where RcF[PCPtBu] = κ3-{2,5-(tBu2PCH2
Externí odkaz:
https://doaj.org/article/902b478d0bbe439c83e89b651c04fc79
Publikováno v:
ARKIVOC, Vol 2008, Iss 4, Pp 120-138 (2008)
Externí odkaz:
https://doaj.org/article/a1bf0b76ecec4eb4bfaf2f74668e115e
Autor:
Natalia V. Belkova, Igor E. Golub, Evgenii I. Gutsul, Konstantin A. Lyssenko, Alexander S. Peregudov, Viktor D. Makhaev, Oleg A. Filippov, Lina M. Epstein, Andrea Rossin, Maurizio Peruzzini, Elena S. Shubina
Publikováno v:
Crystals, Vol 7, Iss 10, p 318 (2017)
Bis(diphenylphosphino)methane copper(I) tetrahydroborate was synthesized by ligands exchange in bis(triphenylphosphine) copper(I) tetrahydroborate, and characterized by XRD, FTIR, NMR spectroscopy. According to XRD the title compound has dimeric stru
Externí odkaz:
https://doaj.org/article/057d64a10a1349818a0b5622ba3c5e74
Autor:
Roman I. Nekrasov, Tat’yana A. Peganova, Ivan V. Fedyanin, Evgenii I. Gutsul, Oleg A. Filippov, Natalia V. Belkova, Alexander M. Kalsin
Publikováno v:
Inorganic Chemistry. 61:16081-16092
Novel 18e̅ and 16e̅ pentamethylcyclopentadienyl rhodium(III) complexes [(η
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::81cec765b36caf7a23527752abe96267
https://doi.org/10.1021/acs.inorgchem.2c02478
https://doi.org/10.1021/acs.inorgchem.2c02478
Autor:
Elena S. Osipova, Daria V. Sedlova, Evgenii I. Gutsul, Yulia V. Nelyubina, Pavel V. Dorovatovskii, Lina M. Epstein, Oleg A. Filippov, Elena S. Shubina, Natalia V. Belkova
Publikováno v:
Organometallics.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::046222fe1815c8503e2500610b96ffa0
https://doi.org/10.1021/acs.organomet.3c00125
https://doi.org/10.1021/acs.organomet.3c00125