Výsledky vyhledávání - "Nasir A, Rajabi"

Seven‐Membered Cyclic Potassium Diamidoalumanyls

Autor: Mary F. Mahon, Han-Ying Liu, Nasir A. Rajabi, Michael S. Hill, Ryan J. Schwamm, Claire L. McMullin

Publikováno v: Chemistry (Weinheim an Der Bergstrasse, Germany)
Schwamm, R, Hill, M, Liu, H-Y D, Mahon, M, McMullin, C & Rajabi, N 2021, ' Seven-membered Cyclic Potassium Diamidoalumanyls ', Chemistry-A European Journal, vol. 27, no. 60, pp. 14971-14980 . https://doi.org/10.1002/chem.202102682

The seven‐membered cyclic potassium alumanyl species, [{SiNMes}AlK]2 [{SiNMes}={CH2SiMe2N(Mes)}2; Mes=2,4,6‐Me3C6H2], which adopts a dimeric structure supported by flanking K‐aryl interactions, has been isolated either by direct reduction of th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::635da52461d9837b4045b99d3314fad1
http://europepmc.org/articles/PMC8596455

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[Ni(NHC) 2 ] as a Scaffold for Structurally Characterized trans [H−Ni−PR 2 ] and trans [R 2 P−Ni−PR 2 ] Complexes

Autor: Michael K. Whittlesey, Sara Sabater, William J. M. Blackaby, Heidi Née Schneider Schmidt, Mary F. Mahon, Nasir A. Rajabi, Udo Radius, Stuart MacGregor, Maximilian W. Kuntze-Fechner, Thomas Zell, Harry Grieve, David Schmidt, John P. Lowe, Connie J. Isaac

Publikováno v: Chemistry – A European Journal. 27:13221-13234

The addition of PPh2 H, PPhMeH, PPhH2 , P(para-Tol)H2 , PMesH2 and PH3 to the two-coordinate Ni0 N-heterocyclic carbene species [Ni(NHC)2 ] (NHC=IiPr2 , IMe4 , IEt2 Me2 ) affords a series of mononuclear, terminal phosphido nickel complexes. Structura

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::32dd488d6ba07dd4b19a56f65ad011f0
https://doi.org/10.1002/chem.202101484

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Ambiphilic Al−Cu Bonding

Autor: Michael S. Hill, Ryan J. Schwamm, Han-Ying Liu, Nasir A. Rajabi, Claire L. McMullin, Mary F. Mahon

Publikováno v: Angewandte Chemie (International Ed. in English)
Hill, M, Liu, H-Y D, Schwamm, R, Mahon, M, McMullin, C & Rajabi, N 2021, ' Ambiphilic Al-Cu Bonding ', Angewandte Chemie-International Edition, vol. 60, no. 26, pp. 14390-14393 . https://doi.org/10.1002/anie.202104658

Copper‐alumanyl complexes, [LCu‐Al(SiNDipp)], where L=carbene=NHCiPr (N,N′‐diisopropyl‐4,5‐dimethyl‐2‐ylidene) and Me2CAAC (1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::442abc6be3ecb5a0628bd6d27688bff5
https://doi.org/10.1002/ange.202104658

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Bonding and Reactivity of a Pair of Neutral and Cationic Heterobimetallic RuZn2 Complexes

Autor: Lia Sotorríos, Mary F. Mahon, Nasir A. Rajabi, Anne-Frédérique Pécharman, Michael K. Whittlesey, Stuart MacGregor, John P. Lowe, Fedor M. Miloserdov

Publikováno v: Inorganic Chemistry 60 (2021) 21
Inorganic Chemistry, 60(21), 16256-16265

A combined experimental and computational study of the structure and reactivity of two [RuZn2Me2] complexes, neutral [Ru(PPh3)(Ph2PC6H4)2(ZnMe)2] (2) and cationic [Ru(PPh3)2(Ph2PC6H4)(ZnMe)2][BArF4] ([BArF4] = [B{3,5-(CF3)2C6H3}4]) (3), is presented.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6427cb92fc07c0f9f6040714db8b4ad
https://doi.org/10.1021/acs.inorgchem.1c02072

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Nucleophilic Magnesium Silanide and Silaamidinate Derivatives

Autor: Robert Kretschmer, Louis J. Morris, Bibian Okokhere-Edeghoghon, Mary F. Mahon, Nasir A. Rajabi, Maximilian Dehmel, Claire L. McMullin, Michael S. Hill

Publikováno v: Okokhere-Edeghoghon, B, Dehmel, M, Hill, M, Kretschmer, R, Mahon, M, McMullin, C, Morris, L & Rajabi, N 2020, ' Nucleophilic Magnesium Silanide and Silaamidinate Derivatives ', Inorganic Chemistry, vol. 59, no. 18, pp. 13679–13689 . https://doi.org/10.1021/acs.inorgchem.0c02034

Density functional theory (DFT) calculations demonstrate that the previously reported reaction of [(BDI)Mgn-Bu] (BDI = HC{(Me)CN-Dipp}2; Dipp – 2,6-di-iso-propylphenyl) with the silaborane, Me2PhSi-Bpin, provides the magnesium silanide derivative,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7300dec708eb777c5fd2a5376c164454
https://doi.org/10.1021/acs.inorgchem.0c02034

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Carbon–Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand

Autor: Martyn P. Coles, Claire L. McMullin, Mathew D. Anker, Nasir A. Rajabi

Publikováno v: McMullin, C, Rajabi, N, Anker, M & Coles, M 2020, ' New Carbon-Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand ', Angewandte Chemie-International Edition . https://doi.org/10.1002/anie.202005301

[K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::896488f00ae225644b6c3dd3fc641069
https://doi.org/10.1002/anie.202005301

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Reductive dehydrocoupling of diphenyltin dihydride with LiAlH4: selective synthesis and structures of the first bicyclo[2.2.1]heptastannane-1,4-diide and bicyclo[2.2.2]octastannane-1,4-diide

Autor: Michaela Flock, David J. Liptrot, Nasir A. Rajabi, Andrew S. S. Wilson, Michael S. Hill, Roland Fischer, Beate Gabriele Steller, Kathrin Tiefling, Claire L. McMullin

Publikováno v: Chemical Communications. 56:336-339

The reaction of diphenyltin dihydride with LiAlH4 gives access to a set of charged tin cages as their lithium salts. Variation in the ratio of reactants provides a perstannabicyclooctane dianion and a perstannanorbornane as the di- and monoanions. Th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7a8ce892e9f290249062f90020fed524
https://doi.org/10.1039/c9cc07976a

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Synthesis and reactivity of alkaline-earth stannanide complexes by hydride-mediated distannane metathesis and organostannane dehydrogenation

Autor: Claire L. McMullin, Mary F. Mahon, Nasir A. Rajabi, Michael S. Hill, Louis J. Morris, Ian Manners

Publikováno v: Dalton Transactions. 49:10523-10534

The synthesis of heteroleptic complexes with calcium- and magnesium-tin bonds is described. The dimeric β-diketiminato calcium hydride complex, [(BDI)Ca(μ-H)]2 (ICa) reacts with Ph3Sn-SnPh3 to provide the previously reported μ2-H bridged calcium s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::66b4e988af4ebf7a7e37fa17aa7273b9
https://doi.org/10.1039/d0dt02406f

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Phosphinoborane interception at magnesium by borane-assisted phosphine-borane dehydrogenation

Autor: Michael S. Hill, Nasir A. Rajabi, Mary F. Mahon, Claire L. McMullin, Ian Manners, Louis J. Morris

Publikováno v: Morris, L J, Rajabi, N A, Hill, M S, Manners, I, McMullin, C L & Mahon, M F 2020, ' Phosphinoborane interception at magnesium by borane-assisted phosphine-borane dehydrogenation ', Dalton Transactions, vol. 49, no. 41, pp. 14584-14591 . https://doi.org/10.1039/d0dt03415k

Reactions of B(C6F5)3 with the β-diketiminato (BDI) alkaline-earth phosphidoborane complexes, 1a [(BDI)Ca(H3B·PPh2)] and 1b [(BDI)Mg(H3B·PPh2)]2 (BDI = [HC{C(CH3)N(2,6-iPr-C6H3)}2]-) result in the formation of phosphinodiboronate complexes 4a [(BD

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f9f3ec19a8e78df861c437d92063024c
https://doi.org/10.1039/d0dt03415k

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