Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Naoto Konya"'
Publikováno v:
Liquid Crystals. 28:1495-1503
We have synthesized new phenylacetylene-based liquid crystals containing a cyclohexyl or cyclohexylethyl group and evaluated their physical properties in order to develop a range of materials having high value of birefringence. The cyclohexyl-contain
Publikováno v:
Liquid Crystals. 28:1375-1387
We have synthesized and investigated new 3-ring phenylacetylene liquid crystals with high birefringence values (Δn) to improve the nematic temperature range while retaining a high optical anisotrop...
Publikováno v:
Liquid Crystals. 28:1361-1367
We have synthesized and evaluated the physical properties of thiophenylacetylene and benzothiazolylacetylene derivatives in order to obtain higher Δn liquid crystals as compared with analogous phenylacetylene-based compounds. These new materials had
Autor:
Naoto Konya, Toru Ashida, Toshihiko Tanaka, Chizu Sekine, Masayoshi Minai, Koichi Fujisawa, Masamitsu Ishitobi
Publikováno v:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 346:209-216
Two kinds of novel molecular materials with high optical anisotropy were synthesized and evaluated. Liquid crystalline phenylacetylene derivatives, which have mesogen of a 1,4-Bis(phenylethynyl)benzene, not only showed high δn but also were stable f
Publikováno v:
Chemistry Letters. 14:1583-1586
The amine-catalyzed Knoevenagel reactions of aldehydes and active methylene compounds containing two activating groups were found to involve many reversible steps, and the diastereomeric intermediary condensation compounds yielded thermodynamically s
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :825
The stereochemistry of the mechanism of the amine-catalyzed Knoevenagel reaction has been studied. Simple treatment of methyl arylsulphinylacetate (1) and aldehydes (2) with a catalytic amount of a secondary amine produced thermodynamically stable E-