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of 10
pro vyhledávání: '"Naoki Hirone"'
Publikováno v:
Advanced Synthesis & Catalysis. 355(No. 9):1736-1740
The iron-catalyzed δ-addition of aryl-Grignard reagents to α,β,γ,δ-unsaturated sulfones proceeded in a regio- and stereoselective manner to give cis-4-aryl-2-alkenyl sulfones. Allylic alkylation of the resultant products was performed without is
Autor:
Hirokazu Urabe, Kirihiro Nakano, Haduki Imade, Shiro Sujaku, Takeshi Hata, Junsuke Imoto, Naoki Hirone
Publikováno v:
Chemistry - A European Journal. 17:14593-14602
Treatment of ethyl (E)-5,5-bis[(benzyloxy)methyl]-8-(N,N-diethylcarbamoyl)-2-octen-7-ynoate with an iron reagent generated from FeCl(2) and tBuMgCl in a ratio of 1:4 (abbreviated as FeCl(2)/4 tBuMgCl) afforded ethyl [4,4-bis[(benzyloxy)methyl]-2-[(E)
Autor:
Kyohei Arayama, Takumi Ishizuka, Ryuji Murayama, Keiichi Hara, Naoki Hirone, Satoshi Okada, Takeshi Hata, Hirokazu Urabe
Publikováno v:
Angewandte Chemie. 120:6966-6970
Publikováno v:
ChemInform. 44
An Fe(II)-catalyzed selective δ-addition of aryl-Grignard reagents to α,β,γ,δ-unsaturated sulfones (I) is presented.
Autor:
Shiro Sujaku, Junsuke Imoto, Haduki Imade, Takeshi Hata, Hirokazu Urabe, Kirihiro Nakano, Naoki Hirone
Publikováno v:
ChemInform. 43
Effective metalative cyclizations of functionalized enynes are accomplished in the presence of a simple iron reagent [ (II)].
Acceleration of the substitution of silanes with Grignard reagents by using either LiCl or YCl3/MeLi
Publikováno v:
Angewandte Chemie (International ed. in English). 49(42)
Publikováno v:
ChemInform. 40
2-Nonen-7-ynedioic or 2-decen-8-ynedioic acid derivatives were treated with an iron reagent generated from FeCl2 and t-BuMgCl in a ratio of 1:4 to give cyclized products after hydrolysis, deuteriolysis, or the addition of carbonyl compounds. Upon rea
Autor:
Takumi Ishizuka, Kyohei Arayama, Naoki Hirone, Keiichi Hara, Takeshi Hata, Ryuji Murayama, Hirokazu Urabe, Satoshi Okada
Publikováno v:
ChemInform. 39
Publikováno v:
Synfacts. 2011:0086-0086
Publikováno v:
Organic Letters. 10(No. 21):5051-5033
2-Nonen-7-ynedioic or 2-decen-8-ynedioic acid derivatives were treated with an iron reagent generated from FeCl2 and t-BuMgCl in a ratio of 1:4 to give cyclized products after hydrolysis, deuteriolysis, or the addition of carbonyl compounds. Upon rea