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Publikováno v:
Physical Chemistry Chemical Physics. 17:28505-28509
Energetic acetone cations decay by methane or methyl radical loss. Although the methane-loss barrier to form the ketene cation is higher and the activation entropy is lower, it has a significant branching ratio at low energies thanks to quantum tunne
Publikováno v:
Physical Chemistry Chemical Physics (PCCP); 11/21/2015, Vol. 17 Issue 43, p28413-28440, 28p
Autor:
Bodi, Andras, Baer, Tomas, Wells, Nancy K., Fakhoury, Daniel, Klecyngier, David, Kercher, James P.
Publikováno v:
Physical Chemistry Chemical Physics (PCCP); 11/21/2015, Vol. 17 Issue 43, p28505-28509, 5p