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pro vyhledávání: '"Nanae Wakamatsu"'
Autor:
Akihiro Ohbayashi, Osamu Kimizuka, Nanae Wakamatsu, Youji Shimomura, Tatsuhiro Goda, Yuji Tokunaga, Kenji Hisada, Norihiro Ohiwa, Susumu Saeki, Koichiro Akasaka
Publikováno v:
The Journal of Organic Chemistry. 75:4950-4956
In this study, we investigated the effect of pressure on the formation and decomplexation of [2]pseudorotaxanes. High pressure accelerated the formation of [2]pseudorotaxanes in an aprotic nonpolar solvent (CDCl(3)/CD(3)CN) via the slipping approach
Effects of Small Structural Changing on the Kinetic and Thermodynamic Stabilities of Pseudorotaxanes
Publikováno v:
HETEROCYCLES. 68:5
Pseudorotaxanes were synthesized in this study. They comprised secondary ammonium ions and 24-membered crown ethers possessing one-four benzene rings fusing macrocycles. Kinetic and thermodynamic stabilities of the complexes were dependent on their n