Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Naima Mokhtari"'
Publikováno v:
Chemical Communications. 56:5905-5908
The superacid-promoted electrophilic Csp3–H bond activation of aliphatic amines generates superelectrophilic species that can be subsequently fluorinated. Demonstrated by low-temperature in situ NMR experiments, the ammonium–carbenium dications,
Autor:
Sébastien Thibaudeau, Hwai-Chien Chan, Phidéline Gérard, Naima Mokhtari, Cédric Theunissen, Nicolas Henry, Christian Bachmann, Agnès Martin-Mingot, Morgan Lecomte, Jérôme Marrot, Benoît Métayer, Guillaume Compain, Gwilherm Evano
Publikováno v:
Organic and Biomolecular Chemistry
Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (20), pp.4399-4416. ⟨10.1039/C7OB00850C⟩
Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (20), pp.4399-4416. ⟨10.1039/C7OB00850C⟩
Polycyclization reactions are among the most efficient synthetic tools for the synthesis of complex, polycyclic molecules in a single operation from simple starting materials. We report in this manuscript a full account on the discovery and developme
Autor:
Ugo Castelli, Sébastien Thibaudeau, Alexandre Le Darz, Jérôme Marrot, Naima Mokhtari, Omar Karam, Fodil Bouazza, Agnès Martin-Mingot
Publikováno v:
Tetrahedron
Tetrahedron, Elsevier, 2016, 72, pp.674-689 ⟨10.1016/j.tet.2015.12.013⟩
Tetrahedron, Elsevier, 2016, 72, pp.674-689 ⟨10.1016/j.tet.2015.12.013⟩
An efficient and straightforward regio-controlled route to β-fluoro-γ-chlorinated amines was developed via an ammonium–chloronium superelectrophilic activation in superacid HF/SbF5. Through halogen directing effect the method was extended to a va
Autor:
Ugo Castelli, Jérôme Marrot, Sébastien Thibaudeau, Omar Karam, Fodil Bouazza, Alexandre Le Darz, Agnès Martin-Mingot, Naima Mokhtari
Publikováno v:
ChemInform. 47
An efficient and straightforward regio-controlled route to β-fluoro-γ-chlorinated amines was developed via an ammonium–chloronium superelectrophilic activation in superacid HF/SbF5. Through halogen directing effect the method was extended to a va
Publikováno v:
ChemInform. 43
Access to enantiopure amino ketones (III) and (X) via a hydrozirconation/transmetalation/ acylation sequence of protected 1-aminobut-3-enes (I) and (X) is reported.
Publikováno v:
Organic letters. 13(23)
Access to nonracemic amino ketones via a hydrozirconation/transmetalation/acylation sequence applied to Boc-protected 1-aminobut-3-enes is presented. This method was applied to the stereoselective synthesis of cyclic imines (or iminiums) which were d