Dinitrogen Coordination to a High-Spin Diiron(I/II) Species

Autor: Juan F. Torres, Collin H. Oi, Ian P. Moseley, Nabila El‐Sakkout, Brian J. Knight, Jason Shearer, Ricardo García‐Serres, Joseph M. Zadrozny, Leslie J. Murray

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2022, 61 (22), pp.e202202329. ⟨10.1002/anie.202202329⟩
Angew Chem Int Ed Engl

International audience; Dinitrogen coordination to iron centers underpins industrial and biological fixation in the Haber-Bosch process and by the FeM cofactors in the nitrogenase enzymes. The latter employ local high-spin metal centers; however, iro

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https://hal.science/hal-03645288