Zobrazeno 1 - 10
of 72
pro vyhledávání: '"N.V. Shokhirev"'
Publikováno v:
Chemical Physics. 196:317-325
Oxygen diffusion in low temperature squalane glasses was studied by phenanthrene phosphorescence quenching and anthracene fluorescence quenching in geminate pairs (anthracene 3. O 2 ). The oxygen mobility can be described by continuous diffusion. Ant
Publikováno v:
Chemical Physics Letters. 236:30-36
The behaviour of nonstationary kinetics of noncontact transfer has been studied on a step-wise model admitting an exact solution. The existence of an intermediate kinetic stage in essentially nonstationary noncontact reactions has been shown.
Upper and lower bounds for the rate constant of bimolecular reactions: integral approximation method
Autor:
A.A. Zharikov, N.V. Shokhirev
Publikováno v:
Chemical Physics Letters. 190:423-429
A method for the calculation of rate constants of bimolecular reactions for an arbitrary type of spherically isotropic transfer probabilities and the interaction potentials between reagents has been developed. On the basis of this method, an integral
Autor:
N.V. Shokhirev, A.A. Zharikov
Publikováno v:
Chemical Physics Letters. 186:253-263
The case of contact reactions of charged particles is considered. For pairs generated in contact, a closed analytical expression for the geminate recombination is derived. The comparison with numerical solution of the Smoluchowksi equation demonstrat
Publikováno v:
Chemical Physics. 154:237-244
The magnetic field effects (MFEs) reported earlier on the recombination products ratio in the reactions of benzyl chloride with triethylgermylsodium (triethylgermylpotassium) have been analyzed. The experimentally observed MFEs prove to be much large
Publikováno v:
Journal of Aerosol Science. 22:373-388
This paper considers the mathematical aspects of the reconstruction of size distribution functions of fine atmospheric aerosol from screen-type diffusion battery (SDB) measurements. It is shown that the problem of reconstruction may be successfully s
Publikováno v:
Chemical Physics. 105:117-126
The inverse problem has been employed to determine the electron-ion pair distance distribution functions, f ( r ), by analysing the experimental dependences of radiation- and photochemical electron yields on the scavenger concentration, g ( c s ), an
Publikováno v:
Chemical Physics. 119:233-240
Bimolecular reactions in solution where the kinematic and reactive properties of the reactants change in time, e.g., as a consequence of relaxation processes, are studied. For this aim a former diffusion-kinetic approximation for the case of slowly v
Publikováno v:
Chemical Physics. 137:207-219
The recombination of charged ion-radicals in the presence of an external magnetic field is studied in the S-T 0 approximation. The non-stationary recombination rate of homogeneous reaction is numerically computed for Boltzmann and uniform initial fun
Publikováno v:
Chemical Physics. 131:315-323
Net low-field CIDNP effects arising in the recombination product of a one-nuclear radical pair (RP) with spin I= 1/2 have been calculated numerically. It is supposed, that besides a major RP recombination channel via singlet (S) state, a minor triple