Výsledky vyhledávání - "N. S. Gurinovich"

Influence of a diimine ligand and an activator on the processes taking place in Brookhart-type nickel catalytic systems

Autor: N. S. Gurinovich, Vitaliy V. Saraev, Ivan V. Saliy, Stanislav K. Petrovsky

Publikováno v: Research on Chemical Intermediates. 44:1935-1944

Brookhart-type catalytic systems based on zero-valent nickel complexes Ni(COD)2 and Ni(COD)L [where COD is cyclooctadiene and L is bis-2,6-diisopropylphenyl-diazabutadiene (DPP-DAB) or N,N′-bis-2,6- diisopropylphenyl-bis-iminoacenaphthene (DPP-BIAN

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::abb8572783e39e576fb3196c1ecfc45b
https://doi.org/10.1007/s11164-017-3207-x

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Study of the nature and mechanism of the formation of paramagnetic species in nickel-based Brookhart-type catalytic systems

Autor: I. V. Salii, V. V. Saraev, N. S. Gurinovich, S. K. Petrovskii

Publikováno v: Kinetics and Catalysis. 57:523-527

The catalytic systems NiBr2(DPP-DAB) + 20 MAO and NiBr2(DPP-BIAN) + 20 MAO (DPP-BIAN = bis(2,6-diisopropylphenyl)-bis(imino)-acenaphtene, MAO = methylaluminoxane), as well as a number of model systems, are studied under conditions of their activation

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::869340c73f38335de6a3800f10b0b3d1
https://doi.org/10.1134/s0023158416040054

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Study of the nature of counterion of α-diimine radical-anion complexes found in Brookhart-type catalytic systems

Autor: D. A. Matveev, V. V. Saraev, P. B. Kraikivskii, N. S. Gurinovich, S. K. Petrovskii, E.B. Kuznetsova

Publikováno v: Journal of Molecular Structure. 1084:302-307

The purpose of this work is to reveal the nature of counterion that stabilizes radical-anions found in Brookhart-type catalytic systems. Radical-anions of two typical α-diimine ligands for Brookhart-type catalytic systems bis(2,6-diisopropylphenyl)d

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1aa6e3f8fa5fe7da2188aa2b3a5bfd58
https://doi.org/10.1016/j.molstruc.2014.12.051

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Electrochemical behavior of nickel bis-(2,6-diisopropylphenyl)diazobutadiene-1,4 dibromide in an aprotic solvent

Autor: D. A. Matveev, V. V. Saraev, P. B. Kraykivskii, S. K. Petrovskii, E. F. Sagitova, N. S. Gurinovich

Publikováno v: Russian Journal of Electrochemistry. 50:239-242

The electrochemical behavior of bis-(2,6-diisopropylphenyl)diazobutadiene-1,4 and its nickel dibromide complex on dropping mercury and glassy carbon electrodes in an aprotic solvent was studied by AC polarography and cyclic voltammetry. Both the liga

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fa9478770f5f5191bcfd62fabda823a3
https://doi.org/10.1134/s1023193514030094

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Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation

Autor: S. K. Petrovskii, D. A. Matveev, V. V. Saraev, N. S. Gurinovich, V. V. Bocharova, P. B. Kraikivskii

Publikováno v: Russian Chemical Bulletin. 62:1323-1326

The formation of two types of paramagnetic species in the catalytic system NiBr2(DAB)/ MAO under real catalytic conditions was found. These are NiII are NiI complexes with the diimine ligand and complexes with the radical anion ligand in the coordina

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f133428078d4fb6f34922a2d1c1fd699
https://doi.org/10.1007/s11172-013-0186-y

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