Zobrazeno 1 - 10
of 17
pro vyhledávání: '"N. M. Rajendran"'
Publikováno v:
The Journal of Organic Chemistry. 86:1246-1252
Reduction of 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1H-imidazol-3-ium chloride (1) resulted in the formation of the first structurally characterized imidazole-based radical 2. 2 was established as a single electron transfer reagent by treating i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6da44fbaf8719888c32ff01b00b69ca6
https://doi.org/10.1021/acs.joc.0c02465
https://doi.org/10.1021/acs.joc.0c02465
Bicyclic (alkyl)(amino)carbene (BICAAC) as a metal-free catalyst for reduction of nitriles to amines
Autor:
Nimisha Gautam, Ratan Logdi, null Sreejyothi P., N. M. Rajendran, Ashwani K. Tiwari, Swadhin K. Mandal
Publikováno v:
Chemical communications (Cambridge, England). 58(18)
Bicyclic (alkyl)(amino)carbene (BICAAC) is introduced as a metal-free catalyst for the reduction of various nitriles to the corresponding amine hydrochloride salts in the presence of pinacolborane. Mechanistic investigations combining experiments and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::125d68c6439943eea777f846f8541ea8
https://pubmed.ncbi.nlm.nih.gov/35156960
https://pubmed.ncbi.nlm.nih.gov/35156960
Autor:
Shubhajit Das, Swapan K. Pati, Arpan Das, Jasimuddin Ahmed, Pallavi Sarkar, N. M. Rajendran, Swadhin K. Mandal, Nimisha Gautam
Publikováno v:
Chemical communications (Cambridge, England). 57(43)
A storable bicyclic (alkyl)(amino)carbene (BICAAC) stabilized two coordinate zinc(0) complex [(BICAAC)2Zn] (2) was synthesized. DFT calculations reveal that BICAAC plays a decisive role in imparting the stability to 2. This complex activates the C(sp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c638f20028dc6dd73b0aa34dc754242e
https://pubmed.ncbi.nlm.nih.gov/33942839
https://pubmed.ncbi.nlm.nih.gov/33942839
Publikováno v:
European Journal of Inorganic Chemistry. 2017:2653-2660
Lithium complexes (Li1-Li5) of tridentate quinolyl-amidinate scaffolds were successfully synthesized in high yields and characterized by 1H NMR, multinuclear solution 7Li NMR spectroscopy. The molecular structures of representative complexes Li2 and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3d9c8b2efdcc4814ae881de9d6aec454
https://doi.org/10.1002/ejic.201700135
https://doi.org/10.1002/ejic.201700135
Publikováno v:
Chemical communications (Cambridge, England). 56(4)
Herein we report an abnormal N-heterocyclic carbene catalyzed dehydration of primary amides in the presence of a silane. This process bypasses the energy demanding 1,2-siloxane elimination step usually required for metal/silane catalyzed reactions. A
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3155f35e863ebde9741dc920143e6088
https://pubmed.ncbi.nlm.nih.gov/31830152
https://pubmed.ncbi.nlm.nih.gov/31830152
Publikováno v:
ChemistrySelect. 1:5660-5665
A series of quinolyl-amidinate compounds ((Ar–N=C(Ph)–N(H)–C9H5N–2–Me: Ar=2,6-Me2C6H3 (L1), 2,6-Et2C6H3 (L2), 2,6-iPr2C6H3 (L3), 2,4,6-Me3C6H2 (L4), 2,6-Et2-4-MeC6H2 (L5)) was synthesized. These compounds in toluene reacted with C2H5MgBr fo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f1e323e97c7059b9f02915e513a560f6
https://doi.org/10.1002/slct.201601517
https://doi.org/10.1002/slct.201601517
Publikováno v:
Comptes Rendus Chimie. 19:604-613
A series of 1-(2,6-dimethyl-4-fluorenylphenylimino)-2-aryliminoacenaphthylene compounds (aryl = 2,6-di(Me)Ph (L1), 2,6-di(Et)Ph (L2), 2,6-di(i-Pr)Ph (L3), 2,4,6-tri(Me)Ph (L4), 2,6-di(Et)-4-MePh (L5)) was prepared and used to form their corresponding
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5f19ead7607a6fe3d3d5df052319aa26
https://doi.org/10.1016/j.crci.2016.01.005
https://doi.org/10.1016/j.crci.2016.01.005
Autor:
Gregory A. Solan, Tongling Liang, Wen-Hua Sun, Qiurui Zhang, Wenjuan Zhang, N. M. Rajendran, Shengdong Wang
Publikováno v:
Inorganic Chemistry Frontiers. 3:1178-1189
A series of sodium 2-arylimino-8-quinolates, C1–C8, differing in both the nature of the aryl and quinolate substituents, was prepared and characterized by 1H/13C NMR spectroscopy and elemental analysis. Their X-ray structures reveal multimetallic a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c0fa941c3590596842e5c83a7f0e5813
https://doi.org/10.1039/c6qi00155f
https://doi.org/10.1039/c6qi00155f
Publikováno v:
Inorganic Chemistry Frontiers. 3:1317-1325
Substituted benzodiazepines of the general formula 2,2′-di(R)-5,6,6′,7′,8,13-hexahydro-5′H-spiro-benzo[2,3][1,4]diazepino[6,5-h]quinoline-7,8′-quinoline [R = H (L1), Me (L2), and Cl (L3)] were synthesized by the condensation reactions betwe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bc71c4bd3304fa3790726c2bf3ba027b
https://doi.org/10.1039/c6qi00177g
https://doi.org/10.1039/c6qi00177g
Publikováno v:
Natural Products and Bioprospecting
This present study reviewed the chemical diversity of marine ascidians and their pharmacological applications, challenges and recent developments in marine drug discovery reported during 1994–2014, highlighting the structural activity of compounds
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b19b2bc7b0c35820f8662c9dce093af7
http://hdl.handle.net/11570/3103321
http://hdl.handle.net/11570/3103321
