Zobrazeno 1 - 10
of 184
pro vyhledávání: '"N. M. Rajendran"'
Publikováno v:
The Journal of Organic Chemistry. 86:1246-1252
Reduction of 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1H-imidazol-3-ium chloride (1) resulted in the formation of the first structurally characterized imidazole-based radical 2. 2 was established as a single electron transfer reagent by treating i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6da44fbaf8719888c32ff01b00b69ca6
https://doi.org/10.1021/acs.joc.0c02465
https://doi.org/10.1021/acs.joc.0c02465
Bicyclic (alkyl)(amino)carbene (BICAAC) as a metal-free catalyst for reduction of nitriles to amines
Autor:
Nimisha Gautam, Ratan Logdi, null Sreejyothi P., N. M. Rajendran, Ashwani K. Tiwari, Swadhin K. Mandal
Publikováno v:
Chemical communications (Cambridge, England). 58(18)
Bicyclic (alkyl)(amino)carbene (BICAAC) is introduced as a metal-free catalyst for the reduction of various nitriles to the corresponding amine hydrochloride salts in the presence of pinacolborane. Mechanistic investigations combining experiments and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::125d68c6439943eea777f846f8541ea8
https://pubmed.ncbi.nlm.nih.gov/35156960
https://pubmed.ncbi.nlm.nih.gov/35156960
Autor:
Shubhajit Das, Swapan K. Pati, Arpan Das, Jasimuddin Ahmed, Pallavi Sarkar, N. M. Rajendran, Swadhin K. Mandal, Nimisha Gautam
Publikováno v:
Chemical communications (Cambridge, England). 57(43)
A storable bicyclic (alkyl)(amino)carbene (BICAAC) stabilized two coordinate zinc(0) complex [(BICAAC)2Zn] (2) was synthesized. DFT calculations reveal that BICAAC plays a decisive role in imparting the stability to 2. This complex activates the C(sp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c638f20028dc6dd73b0aa34dc754242e
https://pubmed.ncbi.nlm.nih.gov/33942839
https://pubmed.ncbi.nlm.nih.gov/33942839
Publikováno v:
European Journal of Inorganic Chemistry. 2017:2653-2660
Lithium complexes (Li1-Li5) of tridentate quinolyl-amidinate scaffolds were successfully synthesized in high yields and characterized by 1H NMR, multinuclear solution 7Li NMR spectroscopy. The molecular structures of representative complexes Li2 and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3d9c8b2efdcc4814ae881de9d6aec454
https://doi.org/10.1002/ejic.201700135
https://doi.org/10.1002/ejic.201700135
Publikováno v:
Chemical communications (Cambridge, England). 56(4)
Herein we report an abnormal N-heterocyclic carbene catalyzed dehydration of primary amides in the presence of a silane. This process bypasses the energy demanding 1,2-siloxane elimination step usually required for metal/silane catalyzed reactions. A
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3155f35e863ebde9741dc920143e6088
https://pubmed.ncbi.nlm.nih.gov/31830152
https://pubmed.ncbi.nlm.nih.gov/31830152
Publikováno v:
ChemistrySelect. 1:5660-5665
A series of quinolyl-amidinate compounds ((Ar–N=C(Ph)–N(H)–C9H5N–2–Me: Ar=2,6-Me2C6H3 (L1), 2,6-Et2C6H3 (L2), 2,6-iPr2C6H3 (L3), 2,4,6-Me3C6H2 (L4), 2,6-Et2-4-MeC6H2 (L5)) was synthesized. These compounds in toluene reacted with C2H5MgBr fo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f1e323e97c7059b9f02915e513a560f6
https://doi.org/10.1002/slct.201601517
https://doi.org/10.1002/slct.201601517
Publikováno v:
Comptes Rendus Chimie. 19:604-613
A series of 1-(2,6-dimethyl-4-fluorenylphenylimino)-2-aryliminoacenaphthylene compounds (aryl = 2,6-di(Me)Ph (L1), 2,6-di(Et)Ph (L2), 2,6-di(i-Pr)Ph (L3), 2,4,6-tri(Me)Ph (L4), 2,6-di(Et)-4-MePh (L5)) was prepared and used to form their corresponding
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5f19ead7607a6fe3d3d5df052319aa26
https://doi.org/10.1016/j.crci.2016.01.005
https://doi.org/10.1016/j.crci.2016.01.005
Autor:
Gregory A. Solan, Tongling Liang, Wen-Hua Sun, Qiurui Zhang, Wenjuan Zhang, N. M. Rajendran, Shengdong Wang
Publikováno v:
Inorganic Chemistry Frontiers. 3:1178-1189
A series of sodium 2-arylimino-8-quinolates, C1–C8, differing in both the nature of the aryl and quinolate substituents, was prepared and characterized by 1H/13C NMR spectroscopy and elemental analysis. Their X-ray structures reveal multimetallic a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c0fa941c3590596842e5c83a7f0e5813
https://doi.org/10.1039/c6qi00155f
https://doi.org/10.1039/c6qi00155f
Publikováno v:
Inorganic Chemistry Frontiers. 3:1317-1325
Substituted benzodiazepines of the general formula 2,2′-di(R)-5,6,6′,7′,8,13-hexahydro-5′H-spiro-benzo[2,3][1,4]diazepino[6,5-h]quinoline-7,8′-quinoline [R = H (L1), Me (L2), and Cl (L3)] were synthesized by the condensation reactions betwe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bc71c4bd3304fa3790726c2bf3ba027b
https://doi.org/10.1039/c6qi00177g
https://doi.org/10.1039/c6qi00177g
Publikováno v:
Polyhedron. 81:329-334
Cu(II) complexes of β-diketiminate ligands with divergent N-aryl substitutions are reported. Exclusive formation of mononuclear [LCu(OAc)] complexes in the case of –CN substituted ligands and hydroxy bridged dinuclear [LCu(OH)]2 complexes in the c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::410b6f72766f707825b8bed462dd2bff
https://doi.org/10.1016/j.poly.2014.05.082
https://doi.org/10.1016/j.poly.2014.05.082