Zobrazeno 1 - 10
of 16
pro vyhledávání: '"N. A. Shpiro"'
Publikováno v:
Russian Chemical Bulletin. 42:760-763
A simple synthesis ofS,3Z-dodecen-11-olide, a component of the aggregation pheromone of the rusty grain beetleCryptolestes ferrugineus (Stephen), was developed. The key stage was Wittig olefination of C9-aldehyde, prepared fromS-propylene oxide, with
Autor:
N. A. Shpiro, V. A. Dragan, V. V. Veselovskii, B. A. Cheskis, A. S. Shashkov, A. M. Moiseenkov
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 27
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:2205-2211
An efficient synthesis of the 3-pentyl ester of 2S-methyl-3R-hydroxypentanoic acid (sitophilate) and its 2S,3S-, 2R,3R-, and 2R,3S-isomers has been carried out starting from the available 2R-methyl-3-butenyl acetate as sole monochiral precursor.
Autor:
V. A. Dragan, B. A. Cheskis, V. V. Veselovskii, A. M. Moiseenkov, A. S. Shashkov, N. A. Shpiro
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1226-1232
New information is discussed concerning the protic and Lewis acid-initiated electrophilic cyclization reaction of α-monoterpenols and their acetates; the distinguishing feature of these reactions is their termination by isopropenyl residues in these
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:716-720
Controlled condensation of propionaldehyde with Li- or Si-enolates, generated from sec-amyl propionate, readily afforded a mixture of diasteromeric 2-methyl-3-hydroxypentanoic acid 3-pentyl esters, which were easily separated by chromatography. The e
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:517-521
The dimerization of methyl acrylate to dimethyl α-methyleneglutarate by the action of tributylphosphine in the absence of a solvent was investigated. Methyl α-methylene-Β-hydroxypentanoate was obtained with a moderate yield by the condensation of
Publikováno v:
ChemInform. 21
Publikováno v:
ChemInform. 21