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Autor:
Sue-Mei Cheah, Jian Yuan, Hui Huang, N Raluca Hurubeanu, Cheryl J. Bourgeois, Arnold L. Rheingold, Russell P. Hughes
Publikováno v:
Canadian Journal of Chemistry. 87:151-160
Oxidative addition of primary, secondary, or benzylic perfluoroalkyl iodides (RF–I) to the phosphine free Ir(I) precursor Ir(acac)(CO)2 1 (acac = 2,4-pentanedionato) proceeds smoothly to afford octahedral Ir(III) products Ir(acac)(I)(RF)(CO)2, A co