One‐dimensional metal–organic frameworks built by coordinating 2,4,6‐tris(4‐pyridyl)‐1,3,5‐triazine linker with copper nodes: CO 2 adsorption properties

Autor: Núria Portolés‐Gil, Oriol Vallcorba, Julio Fraile‐Sainz, Ana M. López‐Periago, Concepción Domingo, José A. Ayllón

Publikováno v: Applied Organometallic Chemistry. 37

The reaction between 2,4,6-tris(4-pyridyl)-1,3,5-triazine (4-tpt) and copper(II) hexafluoroacetylacetone (Cu(hfa)2) yields two different 1D metal–organic frameworks (MOFs), [(Cu(hfa)2)2(4-tpt)]n (1) and [Cu(hfa)2(4-tpt)]n (2). The Cu:4-tpt ratio in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8cb8ee34cc5e5c13fbc14aa698de1b74
https://doi.org/10.1002/aoc.6930

Supramolecular Isomerism in Cobalt(II) Coordination Polymers Built from 3,5-Bis(trifluoromethyl)benzoate and 4,4'-Bipyridine

Autor: Francesco Papi, Albert Rosado, Oriol Vallcorba, Arianna E. Lanza, Mauro Gemmi, Núria Portolés-Gil, Ana M. López-Periago, Concepción Domingo, José A. Ayllón

Publikováno v: Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona
Digital.CSIC. Repositorio Institucional del CSIC
instname

The reaction of [Co2(H2O)(TFMBz)4(py)4] (1) (TFMBz: 3,5-bis(trifluoromethyl)benzoate; py: pyridine) with 4,4′-bipyridine (bpy) in different solvents yields four coordination polymers with unlikely structures but with the same stoichiometry. Three o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::43bb233e31cf4e3e0adcff8b6e7fe40c
https://ddd.uab.cat/record/263039

Single molecule magnets of cobalt and zinc homo- and heterometallic coordination polymers prepared by a one-step synthetic procedure

Autor: Oriol Vallcorba, Silvia Gómez-Coca, Núria Portolés-Gil, Núria Aliaga-Alcalde, José A. Ayllón, Ana M. López-Periago, Gregorio Marbán, Concepción Domingo

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Dipòsit Digital de la UB
Universidad de Barcelona
Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona

The synthesis of 1D cobalt and zinc monometallic and heterometallic coordination polymers (CPs) was carried out applying one-pot synthetic methods by using either supercritical carbon dioxide or ethanol as the solvent. A collection of four 1D CPs wer

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::43e720285a1c501bc533d75bf8602275
https://ddd.uab.cat/record/265207

Supercritical CO2 utilization for the crystallization of 2D metal-organic frameworks using tert-butylpyridine additive

Autor: Núria Portolés-Gil, Oriol Vallcorba, Ana M. López-Periago, Concepción Domingo, José A. Ayllón, Sarah Gowing

Publikováno v: Journal of CO2 Utilization. 24:444-453

Recently, the study of the synthesis of metal-organic frameworks (MOFs) in the presence of supercritical CO2 (scCO2) has become a burgeoning direction in materials science. MOFs crystallization in scCO2 is often carried out in the presence of other s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::364fa17b1e8b147b7e4235a6bea41b94
https://doi.org/10.1016/j.jcou.2018.02.004

Bottom-up approach for the preparation of hybrid nanosheets based on coordination polymers made of metal–diethyloxaloacetate complexes linked by 4,4′-bipyridine

Autor: Ana M. López-Periago, Angel Alvarez-Larena, Concepción Domingo, Ricard Parra-Aliana, Núria Portolés-Gil, José A. Ayllón

Publikováno v: CrystEngComm. 19:4972-4982

In this work, three synthetic approaches were examined to obtain one dimensional (1D) coordination polymers with the formula [M(deox)2(bpy)]∞ (M = Co, Cu, Mn, Ni, Zn) (deox = diethyl oxaloacetate; bpy = 4,4′-bipyridine). These compounds precipita

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1363cdbbc2da509be12241539b4f618f
https://doi.org/10.1039/c7ce00909g