Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Myles P. Harcourt"'
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :1415-1425
Keto-enol tautomeric constants and ionisation constants have been measured for the keto and enol tautomers of 9-formyl-, 9-acetyl- and 9-benzoyl-fluorene in aqueous solution at 25 °C. Values of pKE(KE=[enol]/[ketone] and pKE=–log KE) are –1.22,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2971c671f194b2350d5c635930361682
https://doi.org/10.1039/p29950001415
https://doi.org/10.1039/p29950001415
Publikováno v:
ChemInform. 26
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d079fdf47d1ed91cfc93167ab3cd8d06
https://doi.org/10.1002/chin.199546043
https://doi.org/10.1002/chin.199546043
Publikováno v:
Israel Journal of Chemistry. 26:303-312
Reactivity and selectivity are discussed in terms of quadratic rate—equilibrium relationships for reaction series sharing a common intrinsic barrier, notably Marcus' equation. R.D. Levine's emphasis on such reactions as forming a “Bronsted Series
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d8eb7c75ad8671cf0f669afe0cd95fb9
https://doi.org/10.1002/ijch.198500112
https://doi.org/10.1002/ijch.198500112
Publikováno v:
ChemInform. 19
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e3ea8bda01fec14b8c4c085ba33176b5
https://doi.org/10.1002/chin.198841087
https://doi.org/10.1002/chin.198841087
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :823
Comparisons of equilibrium constants for the hydration of alkenes to form alcohols and of enols to form gem diols show that an oxygen substituent favours hydration as a result of the stabilising geminal interaction of carbon–oxygen bonds in the dio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0af85cc35402c973144e24ba516a3922
https://doi.org/10.1039/c39870000823
https://doi.org/10.1039/c39870000823