Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Murray G. Rosenberg"'
Autor:
Murray G. Rosenberg, Udo H. Brinker
The abstract is available here: https://uscholar.univie.ac.at/o:1637057
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::989450c1aa60c7c8e2d9ffdaee1d3b4a
https://phaidra.univie.ac.at/o:1637057
https://phaidra.univie.ac.at/o:1637057
Autor:
Murray G, Rosenberg, Udo H, Brinker
Publikováno v:
The Journal of Organic Chemistry
Tricyclo[2.1.0.02,5]pent-3-ylidene is a carbene foreseen to rearrange to pyramidane (c-C4H4)C, a highly strained molecule featuring an inverted C atom. Modeling of the carbene, using the (U)MPWB1K/cc-pVTZ//(U)MPWB1K/6-311G(d) theoretical model, indic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::1cf74f7d30554432e87f2829cc20762c
https://pubmed.ncbi.nlm.nih.gov/33355456
https://pubmed.ncbi.nlm.nih.gov/33355456
Autor:
Udo H. Brinker, Murray G. Rosenberg
Tricyclo[2.1.0.02,5]pent-3-ylidene is a carbene foreseen to rearrange to pyramidane (c-C4H4)C, a highly strained molecule featuring an inverted C atom. Modeling of the carbene, using the (U)MPWB1K/cc-pVTZ//(U)MPWB1K/6-311G(d) theoretical model, indic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::374a468b6aacba89baa564ab436834f2
https://phaidra.univie.ac.at/o:1218112
https://phaidra.univie.ac.at/o:1218112
Autor:
Murray G. Rosenberg, Udo H. Brinker
Publikováno v:
Tetrahedron Letters. 59:645-649
The UM06-2X/aug-cc-pVTZ//UM06-2X/6-311G(d) theoretical models of representative singlet trans-2′-substituted cyclobutylcarbenes were computed. The :CH-group of carbenes with an ERG is bent toward the c-C4H7-ring’s proximal C1′–C2′ single bo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e6f4dade73e3c693395cdcba163e9350
https://doi.org/10.1016/j.tetlet.2018.01.006
https://doi.org/10.1016/j.tetlet.2018.01.006
Autor:
Murray G. Rosenberg, Udo H. Brinker
Publikováno v:
The Journal of organic chemistry. 84(18)
Ab initio computations of cyclobutylcarbene (c-C4H7CH) were performed using the UMP4(fc)/6-311++G(2df,2p)//UMP2(full)/6-311++G(d,p) theoretical model. The carbene's most striking feature is its :CH-group. It is markedly bent toward the elongated C1'-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::53ab9df99ca00d940df0df9a8f4a5afa
https://pubmed.ncbi.nlm.nih.gov/31438680
https://pubmed.ncbi.nlm.nih.gov/31438680
Publikováno v:
The Journal of Organic Chemistry. 79:8786-8799
Bromination of the polycyclic oxetane 2,4-oxytwistane (rac-(1R,3S,4R,7S,9R,11S)-2-oxatetracyclo[5.3.1.0(3,11).0(4,9)]undecane) was undertaken in order to form 2,4-dibromotwistane. The oxetane was subjected to the mild reagent combination CBr4/Ph3P in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08c0e91ba09ea267ae4d1ba73c32e736
https://doi.org/10.1021/jo5016129
https://doi.org/10.1021/jo5016129
Publikováno v:
The Journal of organic chemistry. 81(24)
Spiro[3.3]hept-1-ylidene is a markedly strained carbene reaction intermediate that was generated by high-vacuum flash pyrolysis (HVFP) of the corresponding p-tosylhydrazone sodium salt. Five hydrocarbons were produced from the Bamford-Stevens reactan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d06241111864d9e648ad74dd57b9802
https://pubmed.ncbi.nlm.nih.gov/27978720
https://pubmed.ncbi.nlm.nih.gov/27978720
Autor:
Michael M. Bobek, Lothar Brecker, Wolfgang Knoll, Daisuke Kaneno, Udo H. Brinker, Shuji Tomoda, Murray G. Rosenberg
Publikováno v:
The Journal of Organic Chemistry. 77:1340-1360
A study of adamantanylidenes having a γ-substituent (R) was undertaken to gauge how inductive and steric effects of remotely positioned functional groups influence intra- and intermolecular product selectivity. 3H-Diazirines were thermolyzed or phot
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fc90e6f1598e0e7fb2779e6a8bf0194b
https://doi.org/10.1021/jo202132c
https://doi.org/10.1021/jo202132c
Autor:
Udo H. Brinker, Murray G. Rosenberg, Hanspeter Kählig, Vladimir B. Arion, Ingrid Malene Apeland
Publikováno v:
The Journal of organic chemistry. 80(23)
endo-Tricyclo[3.2.1.0(2,4)]oct-8-ylidene is a foiled carbene reaction intermediate. It was generated by thermolyzing Δ(3)-1,3,4-oxadiazoline precursors dissolved in benzaldehyde and acetophenone. The products appear to stem from direct insertion of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd3951292705a0f7ffceb5f57a93b614
https://pubmed.ncbi.nlm.nih.gov/26447842
https://pubmed.ncbi.nlm.nih.gov/26447842
Publikováno v:
ChemInform. 46
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3c8f83c018cf6fa9cc9ada65e7c9d457
https://doi.org/10.1002/chin.201514313
https://doi.org/10.1002/chin.201514313