Výsledky vyhledávání - "Mpf Mark Pepels"

Catalytic Ring-Opening (Co)polymerization of Semiaromatic and Aliphatic (Macro)lactones

Autor: Mpf Mark Pepels, F van der Sanden, Robbert Duchateau, Erik Gubbels

Publikováno v: Macromolecules, 49(12), 4441-4451. American Chemical Society

The ring-opening polymerization (ROP) of cyclic butylene terephthalate oligomers (cBT) using an aluminum salen catalyst was investigated. The kinetic analysis of the ROP of cBT in tetrachloroethane (TCE) revealed a first-order dependence of the rate

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a15fd76c3ad9fd2ad34b33746f2da39
https://doi.org/10.1021/acs.macromol.6b00744

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Compatibility and epitaxial crystallization between poly(ethylene) and poly(ethylene)-like polyesters

Autor: Renate Francisca Tandler, Rob G. Kleijnen, J.G.P. Goossens, Rob Duchateau, Mpf Mark Pepels, Hans Martens, Maria Soliman, AB Anne Spoelstra

Publikováno v: Polymer, 88, 63-70. Elsevier

This work describes the phase behavior of blends of ‘polyethylene-like’ polypentadecalactone (PPDL) and polyethylene. Blends of high-density polyethylene (HDPE) and PPDL were shown to be immiscible at the onset of crystallization of polyethylene,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cadce10dc67bffd2618ab317c1389c78
https://research.tue.nl/en/publications/a2e35e9e-2ada-40af-b572-ec331ab00555

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Molecular Structure-Catalytic Activity Relationship in the Ring-Opening Polymerization of (Macro)lactones

Autor: GJ Geert Noordzij, I Inge Hermsen, Mpf Mark Pepels, Robbert Duchateau

Publikováno v: Macromolecules, 49(3), 796-806. American Chemical Society
Macromolecules, 49(3), 796-806. AMER CHEMICAL SOC

A kinetic analysis on the aluminum salen-catalyzed ring-opening polymerization (ROP) of (macro)lactones is presented, which focuses on how chain transfer agents and the steric hindrance at the alpha-methylene groups of both the growing chain and the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::728a825107f46d8e140e95bca96c0333
https://doi.org/10.1021/acs.macromol.5b02391

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Block copolymers of 'PE-like' poly(pentadecalactone) and poly(L-lactide): synthesis, properties, and compatibilization of polyethylene/poly(L-lactide) blends

Autor: CE Cor Koning, Wilma P. Hofman, Mpf Mark Pepels, Han Goossens, AB Anne Spoelstra, Robbert Duchateau, Rob G. Kleijnen

Publikováno v: Macromolecules, 48(19), 6909-6921. AMER CHEMICAL SOC
Macromolecules, 48(19), 6909-6921. American Chemical Society

Block copolymers consisting of a polyethylene block and a polar polymer block are interesting structures for the compatibilization of polyethylene/polar polymer blends or polyethylene-based composites. Since the synthesis of polyethylene-based block

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a3a94cf8356cbf7bee9ff2599919f63b
https://research.tue.nl/en/publications/f73119bb-f30e-4269-80b2-2657876a849a

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Mimicking (Linear) Low-Density Polyethylenes Using Modified Polymacrolactones

Autor: Rac Ronald Koeken, Andreas Heise, Robbert Duchateau, Mpf Mark Pepels, Sjj Sjoerd Van Der Linden

Publikováno v: Macromolecules, 48(14), 4779-4792. American Chemical Society

This paper presents a new approach toward the introduction of both short- (SCB) and long-chain branching (LCB) in polyethylene-like polyesters via the ring-opening polymerization of macrolactones. Macrolactones containing an alkyl (S1) or alcohol (S2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::560ea72b1fa4818eba53cf25710b7767
https://doi.org/10.1021/acs.macromol.5b00820

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In situ compatibilisation of alkenyl-terminated polymer blends using cross metathesis

Autor: Mpf Mark Pepels, Robbert Duchateau, Camille Descour, Tibor Macko, Ingeborg Schreur-Piet

Publikováno v: RSC Advances, 2015(5), 9658-9666. Royal Society of Chemistry

Several compatibilised polyolefin-based blends have been obtained via rather simple and robust chemistry: olefin cross metathesis using Grubbs' second-generation catalyst (G2) of alkenyl-terminated macromolecules of different nature. The viability of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f775b646998dacae9625c046b6f64ba1
https://doi.org/10.1039/c4ra11056k

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Theoretical and experimental approach to accurately predict the complex molecular weight distribution in the polymerization of strainless Ccyclic esters

Autor: Mpf Mark Pepels, P Paul Soulje, Robbert Duchateau, R. Peters

Publikováno v: Macromolecules, 47(16), 5542-5550. American Chemical Society

Polyesters obtained by the catalytic ring-opening polymerization of macrolactones in many aspects resemble the properties of polyethylene. However, the molecular weight distribution is intrinsically different and equals the molecular weight distribut

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::001872c0a3523782f1a4c561e15ca1e1
https://doi.org/10.1021/ma5015353

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Kinetic Investigation on the Catalytic Ring-Opening (Co)Polymerization of (Macro)Lactones Using Aluminum Salen Catalysts

Autor: Andreas Heise, Miloud Bouyahyi, Mpf Mark Pepels, Robbert Duchateau

Publikováno v: Macromolecules, 46(11), 4324-4334. American Chemical Society

The kinetic behavior of the catalytic ring-opening polymerization (cROP) of a range of macrolactones, including ¿-pentadecalaconte (PDL), ambrettolide (Amb), and butylene adipate (BA), and small-ring lactones, including l-lactide (LLA), e-caprolacto

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d186a0791aa23d6c3f376b96dd4bb69
https://doi.org/10.1021/ma400731c

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Self-healing systems based on disulfide-thiol exchange reactions

Autor: Iaw Ivo Filot, Mpf Mark Pepels, L Bert Klumperman, Jgp Han Goossens

Publikováno v: Polymer Chemistry, 4(18), 4955-4965. Royal Society of Chemistry

New thermoset systems based on disulfide bonds were synthesized with self-healing capabilities. The self-healing mechanism is not related to disulfide–disulfide exchange reactions, but to thiol–disulfide exchange reactions that are pH-dependent.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::194c359e7d3229be001996a64f9afaf6
https://research.tue.nl/en/publications/9811a706-a3b5-482d-88c8-b97988c23893

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