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Publikováno v:
Synthetic Communications. 24:2273-2280
A short synthesis of (3E,5Z)-1,3,5-undecatriene (cis-galbanolene) is described. The key step is the Pd/Cu-catalyzed coupling reaction of (E)-1-chloro-1,3-butadiene with 1-alkynes followed by stereoselective zinc reduction of the triple bond.
Publikováno v:
ChemInform. 26
A short synthesis of (3E,5Z)-1,3,5-undecatriene (cis-galbanolene) is described. The key step is the Pd/Cu-catalyzed coupling reaction of (E)-1-chloro-1,3-butadiene with 1-alkynes followed by stereoselective zinc reduction of the triple bond.