Zobrazeno 1 - 10
of 35
pro vyhledávání: '"Morten B, Ley"'
Publikováno v:
Materials, Vol 8, Iss 9, Pp 5891-5921 (2015)
This review describes recent research in the development of tank systems based on complex metal hydrides for thermolysis and hydrolysis. Commercial applications using complex metal hydrides are limited, especially for thermolysis-based systems where
Externí odkaz:
https://doaj.org/article/020005618d5b4ebc8fc8b72ec296b2d5
Publikováno v:
Energies, Vol 8, Iss 4, Pp 2701-2713 (2015)
The physical properties and the hydrogen release of NaBH4–Mg(BH4)2 and NaBH4−Ca(BH4)2 composites are investigated using in situ synchrotron radiation powder X-ray diffraction, thermal analysis and temperature programmed photographic analysis. The
Externí odkaz:
https://doaj.org/article/bdd6eeca5d1e4cf8b2f08ed444bb6381
Publikováno v:
Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials. 77:299-306
Dehydrocoupling of the adduct of dimethylamine and borane, NH(CH3)2-BH3 leads to dimethylaminoborane with formal composition N(CH3)2-BH2. The structure of this product depends on the conditions of the synthesis; it may crystallize either as a dimer i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ad943fdb2abc914d4dced70939168fb0
https://doi.org/10.1107/s2052520621001979
https://doi.org/10.1107/s2052520621001979
Publikováno v:
Skibsted, J, Payandeh, S, Ley, M B & Jensen, T R 2021, ' 11 B Nuclear Spin-Electron Spin Interactions in 11 B MAS NMR Spectra of Paramagnetic Metal Borohydrides ', Journal of Physical Chemistry C, vol. 125, no. 1, pp. 1113-1124 . https://doi.org/10.1021/acs.jpcc.0c09829
Isotropic and anisotropic couplings between the 11B nuclear spin and the electron spin of paramagnetic electrons are observed in 11B MAS NMR spectra of α-Pr(BH4)3 and LiCe(BH4)3Cl. The 11B NMR spectra of the central and satellite transitions are str
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d49382890ad6d0c2dccf6cc224f17c26
https://pure.au.dk/portal/da/publications/11b-nuclear-spinelectron-spin-interactions-in-11b-mas-nmr-spectra-of-paramagnetic-metal-borohydrides(76e80f5b-20de-486b-b12c-f062a4b8c9da).html
https://pure.au.dk/portal/da/publications/11b-nuclear-spinelectron-spin-interactions-in-11b-mas-nmr-spectra-of-paramagnetic-metal-borohydrides(76e80f5b-20de-486b-b12c-f062a4b8c9da).html
Autor:
Young-Su Lee, Lars H. Jepsen, Torben R. Jensen, Morten B. Ley, Young Whan Cho, Mathias Jørgensen, Jakob B. Grinderslev, Jørgen Skibsted
Publikováno v:
Grinderslev, J B, Ley, M B, Lee, Y S, Jepsen, L H, Jørgensen, M, Cho, Y W, Skibsted, J & Jensen, T R 2020, ' Ammine Lanthanum and Cerium Borohydrides, M(BH 4 ) 3 · nNH 3 ; Trends in Synthesis, Structures, and Thermal Properties ', Inorganic Chemistry, vol. 59, no. 11, pp. 7768-7778 . https://doi.org/10.1021/acs.inorgchem.0c00817
Ammine metal borohydrides show potential for solid-state hydrogen storage and can be tailored toward hydrogen release at low temperatures. Here, we report the synthesis and structural characterization of seven new ammine metal borohydrides, M(BH4)3·
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f785bb0ded84c01686f724a24b7e83c
https://pure.au.dk/ws/files/231050758/Ammine_Lanthanum_and_Cerium_Borohydrides_M_BH4_3_nNH3_Trends_in_Synthesis_Structures_and_Thermal_Properties.pdf
https://pure.au.dk/ws/files/231050758/Ammine_Lanthanum_and_Cerium_Borohydrides_M_BH4_3_nNH3_Trends_in_Synthesis_Structures_and_Thermal_Properties.pdf
Autor:
Jakob B, Grinderslev, Morten B, Ley, Young-Su, Lee, Lars H, Jepsen, Mathias, Jørgensen, Young Whan, Cho, Jørgen, Skibsted, Torben R, Jensen
Publikováno v:
Inorganic chemistry. 59(11)
Ammine metal borohydrides show potential for solid-state hydrogen storage and can be tailored toward hydrogen release at low temperatures. Here, we report the synthesis and structural characterization of seven new ammine metal borohydrides
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::b42b332a82c7ab0fbf99a435e6ca12fd
https://pubmed.ncbi.nlm.nih.gov/32395988
https://pubmed.ncbi.nlm.nih.gov/32395988
Autor:
Roman V. Skoryunov, Alexei V. Soloninin, Terrence J. Udovic, Olga A. Babanova, Morten B. Ley, Torben R. Jensen, Günter Majer, Shin Ichi Orimo, Alexander V. Skripov
Publikováno v:
Skripov, A V, Majer, G, Babanova, O A, Skoryunov, R V, Soloninin, A V, Ley, M B, Jensen, T R, Orimo, S & Udovic, T J 2021, ' Lithium-ion diffusivity in complex hydrides : Pulsed-field-gradient NMR studies of LiLa(BH 4 ) 3 Cl, Li 3 (NH 2 ) 2 I and Li-1-CB 9 H 10 ', Solid State Ionics, vol. 362, 115585 . https://doi.org/10.1016/j.ssi.2021.115585
The bimetallic borohydride-chloride LiLa(BH4)3Cl, the lithium amide-iodide Li3(NH2)2I, and the lithium monocarba-closo-decaborate Li-1-CB9H10 represent complex hydrides showing superionic conductivity at room temperature or slightly above it. To stud
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d97823666c8428cdb7f3c0a80c1affea
https://doi.org/10.1016/j.ssi.2021.115585
https://doi.org/10.1016/j.ssi.2021.115585
Publikováno v:
Ley, M B, Jørgensen, M, Černý, R, Filinchuk, Y & Jensen, T R 2016, ' From M(BH 4 ) 3 (M = La, Ce) Borohydride Frameworks to Controllable Synthesis of Porous Hydrides and Ion Conductors ', Inorganic Chemistry, vol. 55, no. 19, pp. 9748-9756 . https://doi.org/10.1021/acs.inorgchem.6b01526
Inorganic Chemistry, Vol. 55, No 19 (2016) pp. 9748-9756
Inorganic Chemistry
Inorganic Chemistry, Vol. 55, No 19 (2016) pp. 9748-9756
Inorganic Chemistry
Rare earth metal borohydrides show a number of interesting properties e.g. Li ion conductivity and luminescence and the series of materials is well explored. However previous attempts to obtain M(BH4)3 (M = La Ce) by reacting MCl3 and LiBH4 yielded L
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9b2b97bf1b60478d055648d806b60e4d
https://doi.org/10.1021/acs.inorgchem.6b01526
https://doi.org/10.1021/acs.inorgchem.6b01526
Publikováno v:
Energies. 8:1-13
The physical properties and the hydrogen release of NaBH 4 –Mg(BH 4 ) 2 and NaBH 4 −Ca(BH 4 ) 2 composites are investigated using in situ synchrotron radiation powder X-ray diffraction, thermal analysis and temperature programmed photographic ana
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od_______645::990970fddbb61b2946246a0813d7646a
http://www.mdpi.com/1996-1073/8/4/2701/pdf
http://www.mdpi.com/1996-1073/8/4/2701/pdf
Autor:
Dorthe Bomholdt Ravnsbæk, Young-Su Lee, Morten B. Ley, Flemming Besenbacher, Radovan Černý, Young Whan Cho, Torben R. Jensen, Lars H. Jepsen, Jørgen Skibsted
Publikováno v:
Inorganic Chemistry
Inorganic Chemistry, Vol. 54, No 15 (2015) pp. 7402-7414
Haarh Jepsen, L, Ley, M B, Cerny, R, Lee, Y-S, Cho, Y W, Ravnsbæk, D B, Besenbacher, F, Skibsted, J & Jensen, T R 2015, ' Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy) ', Inorganic Chemistry, vol. 54, no. 15, pp. 7402-7414 . https://doi.org/10.1021/acs.inorgchem.5b00951
Jepsen, L H, Ley, M B, Černý, R, Lee, Y-S, Cho, Y W, Ravnsbæk, D, Besenbacher, F, Skibsted, J & Jensen, T R 2015, ' Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH 4 ) 3 · n NH 3 (M = Y, Gd, and Dy) ', Inorganic Chemistry, vol. 54, no. 15, pp. 7402-7414 . https://doi.org/10.1021/acs.inorgchem.5b00951
Inorganic Chemistry, Vol. 54, No 15 (2015) pp. 7402-7414
Haarh Jepsen, L, Ley, M B, Cerny, R, Lee, Y-S, Cho, Y W, Ravnsbæk, D B, Besenbacher, F, Skibsted, J & Jensen, T R 2015, ' Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy) ', Inorganic Chemistry, vol. 54, no. 15, pp. 7402-7414 . https://doi.org/10.1021/acs.inorgchem.5b00951
Jepsen, L H, Ley, M B, Černý, R, Lee, Y-S, Cho, Y W, Ravnsbæk, D, Besenbacher, F, Skibsted, J & Jensen, T R 2015, ' Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH 4 ) 3 · n NH 3 (M = Y, Gd, and Dy) ', Inorganic Chemistry, vol. 54, no. 15, pp. 7402-7414 . https://doi.org/10.1021/acs.inorgchem.5b00951
Fourteen solvent- and halide-free ammine rare-earth metal borohydrides M(BH4)3·nNH3, M = Y, Gd, Dy, n = 7, 6, 5, 4, 2, and 1, have been synthesized by a new approach, and their structures as well as chemical and physical properties are characterized
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7e34d2d5c81671d6133066cd0b7f6875