Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework

Autor: Carter, Joseph H., Han, Xue, Moreau, Florian Y., da Silva, Ivan, Nevin, Adam, Godfrey, Harry G. W., Tang, Chiu C., Yang, Sihai, Schröder, Martin

Publikováno v: Journal of the American Chemical Society
Carter, J H, Han, X, Moreau, F Y, Da Silva, I, Nevin, A, Godfrey, H G W, Tang, C C, Yang, S & Schröder, M 2018, ' Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework ', Journal of the American Chemical Society, vol. 140, no. 46, pp. 15564-15567 . https://doi.org/10.1021/jacs.8b08433

We report a record-high SO2 adsorption capacity of 12.3 mmol g-1 in a robust porous material, MFM-601, at 298 K and 1.0 bar. The SO2 adsorption in MFM-601 is fully reversi-ble and highly selective over CO2 and N2. The binding do-mains for adsorbed SO

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