Zobrazeno 1 - 10
of 89
pro vyhledávání: '"Mordecai Shelef"'
Publikováno v:
The Journal of Physical Chemistry B. 106:4697-4704
Highly dispersed γ-Al2O3-supported PtRu clusters were prepared by decarbonylation of molecularly adsorbed [Pt2Ru4(CO)18] in He or H2 at temperatures in the range of 300−400 °C. Infrared (IR) and extended X-ray absorption fine structure (EXAFS) sp
Autor:
Mordecai Shelef, A.V. Kucherov
Publikováno v:
Catalysis Letters. 75:19-24
In situ ESR at 120–473 K permits to monitor formation of transient paramagnetic ions/complexes (isolated Pd+ sites; Pd+/H2O; Pd+/C6H6) upon interaction of isolated Pd2+ cations stabilized by the H-ZSM-5 matrix with different organic compounds and g
Autor:
A.V. Kucherov, Mordecai Shelef
Publikováno v:
Journal of Catalysis. 195:106-112
A method for the quantitative determination of isolated Fe 3+ ions in FeHZSM-5 by EPR was devised. The method is based on the comparison of signals, taken at −196°C, from pyridine-impregnated catalysts with signals from solutions of Fe(III)-phthal
Autor:
Mordecai Shelef, Robert Walter Mccabe
Publikováno v:
Catalysis Today. 62:35-50
The union of catalysts and the automobile has been one of the greatest successes of heterogeneous catalysis over the last 25 years. Here, the history of automotive catalysis is briefly reviewed, followed by an assessment of where automotive catalysis
Publikováno v:
Journal of Catalysis. 190:157-172
γ-Al 2 O 3 -supported catalysts were prepared from bimetallic precursors, {Pt[W(CO) 3 (C 5 H 5 )] 2 (PhCN) 2 } and {Pt 2 W 2 (CO) 6 (C 5 H 5 ) 2 (PPh 3 ) 2 }, as well as from a mixture of [PtCl 2 (PhCN) 2 ] and [W(CO) 6 ], and characterized by exten
Publikováno v:
Physical Chemistry Chemical Physics. 2:1997-2003
Temperature-programmed desorption (TPD) spectroscopy was used to characterize the desorption of H2 from γ-Al2O3-supported samples prepared from {Pt[W(CO)3(C5H5)]2(PhCN)2} and {Pt2W2(CO)6(C5H5)2(PPh3)2} as well as those prepared from [PtCl2(PhCN)2] a
Publikováno v:
Applied Catalysis B: Environmental. 21:243-258
In metal-free ZSM-5, the decrease in the concentration of Bronsted and Lewis acid sites parallels the increase in the SiO2/Al2O3 ratio. In the presence of residual moisture, the adsorption of small alkanes does not markedly depend on the SiO2/Al2O3 r
Publikováno v:
Journal of Catalysis. 185:170-181
Samples of Pt on γ-Al2O3 were prepared by reduction in H2 at 400°C of [PtCl2(PhCN)2], adsorbed intact from n-pentane solution onto γ-Al2O3 powder that had been partially dehydroxylated under vacuum at 400°C. The Pt dispersion was determined to be
Publikováno v:
Physical Chemistry Chemical Physics. 1:5725-5733
γ-Al2O3-supported catalysts were prepared from molecular bimetallic precursors, {Pt[W(CO)3(C5H5)]2(PhCN)2} and {Pt2W2(CO)6(C5H5)2(PPh3)2}; samples for comparison were prepared from mononuclear precursors, [PtCl2(PhCN)2] or a mixture of [PtCl2(PhCN)2
Publikováno v:
Applied Catalysis B: Environmental. 16:245-254
In 2.2% Rh/γ-Al2O3, the vast majority of the Rh, >95%, is ESR inactive. The rest, a small proportion, can be made ESR-visible by room temperature sorption of water or other polar molecules suggesting that the interaction of these ESR-active ions wit