Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Montserrat Alfonso"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 8, Pp 1214-1218 (2016)
The isotypic title one-dimensional coordination polymers, [CdCl2(C18H14N4O4)]n, (I), and [HgCl2(C18H14N4O4)]n, (II), are, respectively, the cadmium(II) and mercury(II) complexes of the dimethyl ester of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic
Externí odkaz:
https://doaj.org/article/cc13d0c6646047f3b129b8398e6a1ec8
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 2, Pp 233-237 (2016)
In dimethyl 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylate, C18H14N4O4, (I), and diethyl 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylate, C20H18N4O4, (II), the dimethyl and diethyl esters of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic acid, the o
Externí odkaz:
https://doaj.org/article/ec10c1c1a76b44d3b1e832e03f215e19
Publikováno v:
CHIMIA, Vol 57, Iss 10 (2003)
When they come into contact with air, coordination compounds can often change their appearance. For instance, the colour of the compound can change as transparent crystals become opaque microcrystalline solids. This visible transformation of the comp
Externí odkaz:
https://doaj.org/article/0a2ce2bc1088462f8f2e0d0686d9d691
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 2, Pp 233-237 (2016)
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications
In compound (I), the dimethyl ester of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic acid, pyridine ring B is inclined to pyrazine ring A by 44.8 (2)°. The Npyrazine—C—C—Npyridine torsion angle is −133.7 (4)°, with the N atoms tran
Autor:
Heinz Berke, Helmut W. Schmalle, Thomas Fox, Johan Cugny, Montserrat Alfonso, Olivier Blacque
Publikováno v:
European Journal of Inorganic Chemistry. 2006:540-552
Starting from Mo(N2)2(depe)2 (1), the nitrido complex Mo(N)(N3)(depe)2 (2) was obtained by the reaction of 1 with Me3SiN3. Subsequent reaction of 2 with HCl in CH3OH afforded the cationic imido chloride 3, which could be converted into the nitrido ch
Autor:
Sohrab Kheradmandan, Thomas Fox, Heinz Berke, Montserrat Alfonso, Olivier Blacque, Helmut W. Schmalle, Koushik Venkatesan
Publikováno v:
Organometallics. 24:920-932
The mononuclear vinylidene complexes of the type Mn(C5H4R‘)(R‘ ‘2PCH2CH2PR‘ ‘2)(CC(R1)(SnMe3)) were obtained by the reaction of Mn(C5H4R‘)(η6-cycloheptatriene) (R‘ = H, 1a; CH3, 1b) with 1 equiv of R1−C⋮C−SnMe3 (R1 = SnMe3, C6H5,
Autor:
Heinz Berke, and Helmut W. Schmalle, Thomas Fox, Koushik Venkatesan, Montserrat Alfonso, Olivier Blacque
Publikováno v:
Organometallics. 23:4661-4671
The vinylalkynyl complexes Mn(C5H4R‘)(R‘ ‘2PCH2CH2PR‘ ‘2)(CCSnPh3C⋮CSnPh3) (5, 6) were obtained in good yields by treatment of Mn(C5H4R‘)(η6-cycloheptatriene) (R‘ = H (1a), Me (1b)) with 1 equiv of Ph3SnC⋮CC⋮CSnPh3 and R‘ ‘2P
Publikováno v:
Russian Chemical Bulletin. 53:1116-1120
The reaction of [Re(NO)2(PR3)2][BArF 4] (R = cyclo-C6H13 (1a), Pri (1b); [BArF 4]– = [B(3,5-(CF3)2C6H3)4]) with phenylacetylene in the presence of a non-nucleophilic base, like 2,6-bis(tert-butyl)pyridine (BTBP) or ButOK, affords the phenylethynyl
Autor:
Helmut W. Schmalle, Montserrat Alfonso, Heinz Berke, Koushik Venkatesan, Thomas Fox, Olivier Blacque
Publikováno v:
Organometallics. 23:1183-1186
Vinylidene species of the type Mn(C5H4CH3)[(H3C)2PCH2CH2P(CH3)2](CCR1R2) (R1 = R2 = H; R1 = H, R2 = Ph) can be fully reversibly coupled to yield the dinuclear complexes [(C5H4CH3)(dmpe)Mn⋮CC(R1)(R2)C(R1)(R2)C⋮Mn(dmpe)(C5H4CH3)][PF6]2 (R1, R2 = H;
Publikováno v:
Journal of Organometallic Chemistry. 689:801-810
The ruthenium and iron dicarbonyl complexes Ru(MeP(CH 2 CH 2 PMe 2 ) 2 )(CO) 2 ( 1 ), Ru(MeP(CH 2 CH 2 CH 2 PMe 2 ) 2 )(CO) 2 ( 2 ) and Fe(MeP(CH 2 CH 2 CH 2 PMe 2 ) 2 )(CO) 2 ( 3 ) bearing strong donor tridentate phosphine ligands were prepared and