Zobrazeno 1 - 10
of 22
pro vyhledávání: '"Monika Moszner"'
Autor:
Monika Moszner
Publikováno v:
Inorganica Chimica Acta. 357:3613-3620
The decaaqua-di-rhodium(II) cation has been found to be an interesting starting material in the preparation of dioxygen complexes with different N-donor ligands. Treatment of aqueous HClO 4 solution of [Rh 2 (H 2 O) 10 ] 4+ with NH 4 OH/NH 3 , py and
Publikováno v:
Inorganica Chimica Acta. 357:2483-2493
Hexaaquarhodium(III) perchlorate has been found to be an interesting starting material for the preparation of rhodium compounds. New mononuclear hydrido- and carbonylrhodium compounds with bis(benzimidazol-2-ylmethyl)methylamine (L) and PPh 3 of the
Autor:
Tomasz Ganicz, Robert J. Perry, Michael Joseph O'brien, Wlodzimierz A. Stanczyk, Urszula Mizerska, Monika Moszner
Publikováno v:
Applied Catalysis A: General. 259:49-55
The catalytic activity and selectivity of a series of rhodium(I), (II) and (III) complexes have been examined in a model hydrosilylation reaction of 1-octene with triethoxysilane and in a more applied system composed of oligomeric allyl ethoxylate al
Publikováno v:
Inorganica Chimica Acta. 357:115-124
The reaction between [Rh(H2O)6](ClO4)3 and the monoanion Hdopn− (H2dopn=bis(diacetylmonoxime-imino)propane 1,3=3,9-dimethyl-4,8-diazaundeca-3,8-diene-2,10-dione dioxime) afforded a new dimeric rhodium(II) compound of formula [Rh(Hdopn)(H2O)]2(ClO4)
Publikováno v:
Polyhedron. 22:3195-3203
Treatment of [Rh(Hdmg)2(PPh3)Cl] with zinc amalgam afforded a heterobimetallic compound [Rh(Hdmg)(ClZndmg)(PPh3)Cl] (1a) (Hdmg=monoanion of dimethylglyoxime). Crystallization of (1a) from a CHCl3/C2H5OH mixture led to the formation of [Rh(Hdmg){ClZn(
Publikováno v:
Journal of Organometallic Chemistry. 595:178-185
The complex Tp Ph,Me Rh(CO) 2 ( 1 ) was prepared from the reaction of the appropriate potassium pyrazolyl borate, Tp Ph,Me K, with Rh(acac)(CO) 2 in warm benzene. Reaction of Rh(acac)(CO) 2 with Tp Ph,Me K and PPh 3 gave the compound Tp Ph,Me Rh(CO)(
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 130:241-248
Rhodium(II) complexes with dioximes [Rh(Hdmg) 2 (PPh 3 )] 2 [ I ] (Hdmg=monoanion of dimethylglyoxime) and [Rh(Hdmg)(ClZndmg)(PPh 3 )] 2 [ II ] catalyse hydroformylation and hydrogenation reactions of 1-hexene at 1 MPa CO/H 2 and 0.5 MPa H 2 at 353 K
Publikováno v:
Inorganica Chimica Acta. 261:161-167
Preparations of [Rh(Hdmg) 2 (H 2 O) 2 ]ClO 4 ( 1 ) (Hdmg=dimethylgyoximate) from [Rh(H 2 O) 6 ](ClO 4 ) 3 and dimethylglyoxime and of [Rh(Hdmg) 2 (PPh 3 ) 2 ]ClO 4 ( 2 ) from 1 and PPh 3 are described. 1 crystallizes in the space group with a =14.910
Autor:
Tadeusz Głowiak, Monika Moszner, J.J. Ziółkowski, Giacomo Costa, Maria Kubiak, Claudio Tavagnacco
Publikováno v:
Polyhedron. 16:307-313
The reaction of RhCl 3 ·3H 2 O with Hdamo and PPh 3 (Hdamo = diacetyl monoxime = C 4 H 7 NO), both in the absence ( 1 ) and in the presence of HClO 4 ( 2 ) afforded the complex Rh(damo)(PPh 3 ) 2 Cl 2 . The reaction of the acidic water/ethanolic sol
Publikováno v:
Polyhedron. 13:1351-1354
The electrochemical oxidation of yellow basic solutions containing hydrolysed Rh 3+ results in the formation of blue superoxo-rhodium(III). The products of oxidation (electrochemical and chemical) of aqueous rhodium(III) are rationalized.