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pro vyhledávání: '"Monica V. Shree"'
Multiple C–H Activations of Linear Alkanes by Various (η5-Cyclopentadienyl)W(NO)(CH2CMe3)2 Complexes
Autor:
Monica V. Shree, Devon C. Rosenfeld, Guillaume Lefèvre, Diana Fabulyak, Aurélien Béthegnies, Kevan E. Dettelbach, Peter Legzdins, Brian O. Patrick, Rhett A. Baillie
Publikováno v:
Organometallics. 36:2714-2726
As illustrated in the accompanying diagram, thermolysis of Cp*W(NO)(CH2CMe3)2 (Cp* = η5-C5Me5) at 80 °C in neat linear alkanes effects three successive C–H bond activations of the hydrocarbon substrates and forms Cp*W(NO)(H)(η3-allyl) complexes
Autor:
Peter Legzdins, Rhett A. Baillie, Michelle E. Thibault, Catherine Chow, Renee W. Y. Man, Monica V. Shree, W. Stephen McNeil
Publikováno v:
Organometallics. 30:6201-6217
Thermolysis of Cp*W(NO)(CH2CMe3)(η3-CH2CHCHPh) (1) at 55 °C leads to the loss of neopentane and the formation of the 16e η2-allene intermediate complex Cp*W(NO)(η2-CH2═C═CHPh) (A), which has been i...
Autor:
Russell J. Wakeham, Devon C. Rosenfeld, Peter Legzdins, Rhett A. Baillie, Monica V. Shree, Guillaume Lefèvre, Brian O. Patrick, Aaron S. Holmes
Publikováno v:
Inorganic chemistry. 54(12)
Sequential treatment at low temperatures of Cp*W(NO)Cl2 in THF with 1 equiv of a binary magnesium allyl reagent, followed by an excess of LiBH4, affords three new Cp*W(NO)(H)(η(3)-allyl) complexes, namely, Cp*W(NO)(H)(η(3)-CH2CHCMe2) (1), Cp*W(NO)(