Zobrazeno 1 - 10 of 74 pro vyhledávání: '"Monica Trincado"'
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Akademický článek
Trigonal Bipyramidal Rhodium(I) Methyl and Phenyl Complexes: Precursors of Oxidative Methyl and Phenyl Radical Generation
Autor: Urs Fischbach, Matthias Vogt, Peter Coburger, Monica Trincado, Hansjörg Grützmacher
Publikováno v: Inorganics, Vol 10, Iss 3, p 28 (2022)
The new complexes [Rh(Me)(trop3P)] (2) and [Rh(Ph)(trop3P)] (3) (trop = 5H-dibenzo[a,d]cyclohepten-5-yl) were synthesised by addition of organolithium reagents (MeLi and PhLi) to the parent pentacoordinated chloride complex [RhCl(trop3P)]. The compou
Externí odkaz: https://doaj.org/article/a151d6d3f1044bd091bc5c90289cf8e1
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2
Reduction of Nitrous Oxide by Light Alcohols Catalysed by a Low‐Valent Ruthenium Diazadiene Complex
Autor: Jonas Bösken, Rafael E. Rodríguez‐Lugo, Sven Nappen, Monica Trincado, Hansjörg Grützmacher
Publikováno v: Chemistry-A European Journal, 29 (20)
Decomposition of the environmentally harmful gas nitrous oxide (N2O) is usually performed thermally or catalytically. Selective catalytic reduction (SCR) is currently the most promising technology for N2O mitigation, a multicomponent heterogeneous ca
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aac7751c4e4d0bda19c6a8a93864b409
https://doi.org/10.1002/chem.202203632
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3
Reduction of Nitrogen Oxides by Hydrogen with Rhodium(I)–Platinum(II) Olefin Complexes as Catalysts
Autor: Sébastien Gauthier, Fabian Müller, Pascal Jurt, Juan José Gamboa-Carballo, Hansjörg Grützmacher, Michael Wörle, Anne Sofie Abels, Monica Trincado, Grégoire Le Corre, Frederik Eiler, Matthew G. Baker, Thomas L. Gianetti, Marcel Aebli, Israel Fernández, René Verel
Publikováno v: Angewandte Chemie. International Edition, 60 (48)
The nitrogen oxides NO2, NO, and N2O are among the most potent air pollutants of the 21st century. A bimetallic RhI–PtII complex containing an especially designed multidentate phosphine olefin ligand is capable of catalytically detoxifying these ni
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::724627804d761c7dc3e288b845bb9cc7
https://doi.org/10.1002/ange.202109642
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4
Computational mechanistic studies of ruthenium catalysed methanol dehydrogenation
Autor: Felix J. de Zwart, Vivek Sinha, Monica Trincado, Hansjörg Grützmacher, Bas de Bruin
Publikováno v: Dalton Transactions, 51(8), 3019-3026. Royal Society of Chemistry
Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry, 51(8)
Dalton Transactions, 51 (8)
Homogeneous ruthenium catalysed methanol dehydrogenation could become a key reaction for hydrogen production in liquid fuel cells. In order to improve existing catalytic systems, mechanistic insight is paramount in directing future studies. Herein, w
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d774e4eae8ea7ea65cb6b8ab18c03f6f
https://dare.uva.nl/personal/pure/en/publications/computational-mechanistic-studies-of-ruthenium-catalysed-methanol-dehydrogenation(41af1df5-941a-4ef2-a193-b92717955083).html
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6
An In-Depth Mechanistic Study of Ru-Catalysed Aqueous Methanol Dehydrogenation and Prospects for Future Catalyst Design
Autor: Monica Trincado, Vivek Sinha, Hansjörg Grützmacher, Evert Jan Meijer, Bas de Bruin, Nitish Govindarajan
Publikováno v: ChemCatChem, 12 (9)
ChemCatChem, 12(9), 2610-2621. Wiley
Herein we provide mechanistic insights into the dehydrogenation of aqueous methanol catalysed by the [Ru(trop2dae)] complex (which is in‐situ generated from [Ru(trop2dad)], trop2dad=1,4‐bis(5H‐dibenzo[a,d]cyclohepten‐5‐yl)‐1,4‐diazabuta
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0567e384b36516408040ec16b7f5c278
https://hdl.handle.net/20.500.11850/409072
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7
DFT Provides Insight into the Additive-Free Conversion of Aqueous Methanol to Dihydrogen Catalyzed by [Ru(trop2dad)]: Importance of the (Electronic) Flexibility of the Diazadiene Moiety
Autor: Monica Trincado, Bas de Bruin, Vivek Sinha, Hansjörg Grützmacher
Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, 140(40), 13103-13114. American Chemical Society
Journal of the American Chemical Society, 140 (40)
The mechanism for complete dehydrogenation of aqueous methanol to CO2 and three equivalents of H2 catalyzed by [Ru(trop2dad)] was investigated with DFT (trop2dad = 1,4-bis(5H-dibenzo[a,d]cyclohepten-5-yl)-1,4-diazabuta-1,3-diene). To date, this is th
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c5fadad1e9c645b6a6d1539bcf3dd2b
https://hdl.handle.net/11245.1/dd9bc9d9-c74b-4c5b-82a0-fac291e2fcba
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8
Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious
Autor: Hansjörg Grützmacher, Vivek Sinha, Bas de Bruin, Bruno Pribanic, Monica Trincado
Publikováno v: Chemistry-A European Journal, 24 (21)
Chemistry (Weinheim an Der Bergstrasse, Germany)
Chemistry-A European Journal, 24(21), 5513-5521. Wiley-VCH Verlag
Coordination of the diazadiene diolefin ligand (trop2dad) to ruthenium leads to various complexes of composition [Ru(trop2dad)(L)]. DFT studies indicate that the closed‐shell singlet (CSS), open‐shell singlet (OSS), and triplet electronic structu
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3651eaeb2475fe9172f444d51f4ebc74
https://hdl.handle.net/11245.1/5da62121-5abf-4a00-9be8-400808a9fe71
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9
Homogeneously catalyzed acceptorless dehydrogenation of alcohols: A progress report
Autor: Monica Trincado, Hansjörg Grützmacher, Jonas Bösken
Publikováno v: Coordination Chemistry Reviews, 443
Catalytic dehydrogenation of alcohols represents an attractive approach for future applications as hydrogen storage systems and clean synthesis of fine chemicals. Herein, an overview of recent progress in homogeneously catalyzed acceptorless alcohol
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00efdf4a86ce8e030fd8561c7418eb67
https://doi.org/10.1016/j.ccr.2021.213967
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10
A Stable Aminyl Radical Coordinated to Cobalt
Autor: Bas de Bruin, Monica Trincado, Rafael E. Rodríguez-Lugo, Hansjörg Grützmacher
Publikováno v: Chemistry-A European Journal, 23 (28)
Chemistry-A European Journal, 23(28), 6795-6802. Wiley-VCH Verlag
A family of cobalt complexes bearing the trop2NH [bis(5‐H‐dibenzo[a,d]cyclohepten‐5‐yl)‐amine] and 2,2’‐bpy (2,2’‐bipyridine) chelate ligands were prepared and fully characterized. The compounds [Co(trop2N)(bpy)], [Co(trop2NH)(bpy)]
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a3c4fd778deb235eba8f8f19094d38c9
https://doi.org/10.1002/chem.201605624
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