Protein modification via alkyne hydrosilylation using a substoichiometric amount of ruthenium(II) catalyst

Autor: Fengzhi Zhang, Stephen J. Walsh, Moni K. Gupta, Gonçalo J. L. Bernardes, Martin Welch, Elizabeth C. Frye, Terence T.-L. Kwan, Omar Boutureira, Hannah F. Sore, Jason W. Chin, Yuteng Wu, David R. Spring, Stephen Wallace, Warren R. J. D. Galloway

Publikováno v: Kwan, T T-L, Boutureira, O, Frye, E C, Walsh, S J, Gupta, M K, Wallace, S, Wu, Y, Zhang, F, Sore, H F, Galloway, W R J D, Chin, J W, Welch, M, Bernardes, G J L & Spring, D R 2017, ' Protein Modification via Alkyne Hydrosilylation Using A Substoichiometric Amount of Ruthenium(II) Catalyst ', Chemical Science, vol. 8, no. 5, pp. 3871-3878 . https://doi.org/10.1039/C6SC05313K
Chemical Science

Transition metal catalysis has emerged as a powerful strategy to expand synthetic flexibility of protein modification. Herein, we report a cationic Ru(II) system that enables the first example of alkyne hydrosilylation between dimethylarylsilanes and

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https://www.repository.cam.ac.uk/handle/1810/264391