Výsledky vyhledávání - "Mohan M. Gamage"

Mechanistic Pathways for N2O Elimination from trans-R3Sn-O-N═N-O-SnR3 and for Reversible Binding of CO2 to R3Sn-O-SnR3 (R = Ph, Cy)

Autor: Manuel Temprado, Jack V. Davis, Carl D. Hoff, Mohan M. Gamage, Oswaldo Guio, Burjor Captain

Publikováno v: Inorganic Chemistry. 60:12075-12084

The rate and mechanism of the elimination of N2O from trans-R3Sn-O-N═N-O-SnR3 (R = Ph (1Ph) and R = Cy (1Cy)) to form R3Sn-O-SnR3 (R = Ph (2Ph) and R = Cy (2Cy)) have been studied using both NMR and IR techniques to monitor the reactions in the tem

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::aff44e71fc6dbce2f6a04963219f38e4
https://doi.org/10.1021/acs.inorgchem.1c01291

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Mechanistic Pathways for N

Autor: Jack V, Davis, Mohan M, Gamage, Oswaldo, Guio, Burjor, Captain, Manuel, Temprado, Carl D, Hoff

Publikováno v: Inorganic chemistry. 60(16)

The rate and mechanism of the elimination of N

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e300a140098c2790ef7e18fe265514b1
https://pubmed.ncbi.nlm.nih.gov/34338521

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Mixed-Metal Cluster Complexes from the Reactions of M3(CO)12 (M = Fe, Ru, Os) with the Unsaturated Complex Pt(IPr)(SnBut3)(H)

Autor: Mohan M. Gamage, Burjor Captain, Vincent Zollo, Sedigheh Etezadi

Publikováno v: Journal of Cluster Science. 30:1355-1361

The reaction of Ru3(CO)12 with Pt(IPr)(SnBut3)(H) at 68 °C yielded the trigonal bipyramidal cluster Ru3Pt2(IPr)2(CO)12, 1, in 32% yield. The reaction of Os3(CO)12 with Pt(IPr)(SnBut3)(H) at 68 °C furnished the triosmium–monoplatinum cluster compl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::45c26e05fe223257643aa8624c56959f
https://doi.org/10.1007/s10876-019-01665-x

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Coordination Chemistry of Heavier Group 13 and 14 Ligands in Transition Metal Complexes

Autor: Burjor Captain, Mohan M. Gamage

Publikováno v: Comprehensive Coordination Chemistry III ISBN: 9780081026892
Comprehensive Coordination Chemistry III

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f281c4203329356b9fc4362a829b2152
https://doi.org/10.1016/b978-0-08-102688-5.00093-3

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Thermal and catalytic decomposition of trans bis-stannyl hyponitrites

Autor: Mohan M Gamage

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::09451dd5a14eed823ee87cca3bf4b8f6
https://doi.org/10.1021/scimeetings.0c03858

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The mechanism of carboxylative cyclization of propargylamine by N-heterocyclic carbene complexes of Au(I)

Autor: Mohan M. Gamage, Carl D. Hoff, Oswaldo Guio, Burjor Captain, Jack V. Davis, Manuel Temprado, Steven P. Nolan, Tahani Al Chami Al Bayrakdar

Publikováno v: JOURNAL OF ORGANOMETALLIC CHEMISTRY

The complex [Au(IPr)(2-oxazolidinone)] (1 = IKa) was prepared from reaction of [Au(IPr)Cl] (2), K2CO3, and propargyl amine (PPA). Kinetic studies have been performed for acid cleavage of 1 to yield the oxazolidinone product and an [Au(IPr)(X)] adduct

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::857530ab4686bfd223ee3369fbf0b412
https://biblio.ugent.be/publication/8715004

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Activation of small molecules by the unsaturated complex Pt(IBut)(PBut3): First structural characterization of a peroxycarbonate complex of platinum

Autor: Mark D. Smith, Burjor Captain, Mohan M. Gamage

Publikováno v: Journal of Organometallic Chemistry. :121900

The reaction of Pt(COD)2 with one equivalents of IBut and PBut3 at room temperature yields the unsaturated platinum mixed N-heterocyclic carbene and phosphine complex Pt(IBut)(PBut3), 1. Complex 1 reacts rapidly with O2 and CO to form the dioxygen ad

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::13c673d4c712a58e61486ef349e9105a
https://doi.org/10.1016/j.jorganchem.2021.121900

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Intermediates and catalytic hydrostannylation. Characterization of a rare complex Pt(IPr)[η2-E-(SnBut3)(H)C C(SiMe3)(H)]

Autor: Burjor Captain, Mohan M. Gamage, Anjaneyulu Koppaka

Publikováno v: Journal of Organometallic Chemistry. :233-236

The complex Pt(IPr)(SnBut3)(H), 1 [IPr=N-heterocylic carbene ligand N,N’-bis-(2,6-(diisopropyl)phenyl)imidazol-2-ylidene] reacts with trimethylsilylacetylene to yield the C-H activation product Pt(IPr)(SnBut3)(κ1-C≡CSiMe3)(H)2, 2. Complex 2 isom

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fc961719bb3dd3e5baf4350f00dedac4
https://doi.org/10.1016/j.jorganchem.2017.03.024

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Investigations of tri-t-butyl tin hydride complexes of transition metals in small molecule activation and catalysis

Autor: Mohan M. Gamage, Sedigheh Etezadi, Burjor Captain, Anjaneyulu Koppaka

Publikováno v: Journal of Organometallic Chemistry. 848:122-132

Transition metal complexes containing the sterically encumbered SnBut3 group are the focus of this brief review. The ability of tin compounds to modify both heterogeneous and homogeneous catalysts has been known for some time. Our recent efforts cent

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c0f8dc968c03878bb6cd0830ab5b6fc3
https://doi.org/10.1016/j.jorganchem.2017.07.024

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