Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Mitsuhiro Asakura"'
Publikováno v:
Tetrahedron. 74:2405-2413
Experimental and theoretical studies on the thermodynamics and properties of 2-substituted 6(4)-methyl-1,4(1,6)-dihydropyrimidine-5-carboxylates were undertaken by 1H NMR measurements and DFT (density functional theory) calculations. The ratios of ta
Autor:
Nobuhiro Morita, Takanori Hirose, Tatsuya Sakaue, Yoshitaka Toyofuku, Mitsuhiro Asakura, Shinji Toyota, Michinori Oki
Publikováno v:
Russian Journal of Organic Chemistry. 39:542-553
X-ray crystallography of the ap-form of the 1-(9-fluorenyl)-2-(2-methyl-2-oxiranyl)naphthalene has revealed that the carbon atom of the oxirane which is connected to the naphthyl group in this compound is almost planar. The specific structural featur
Publikováno v:
Bulletin of the Chemical Society of Japan. 75:2667-2671
The title carbonyl compounds bearing a 4,4-diphenyl-1,3,2-dioxaborolan-2-yl group at the ortho position were prepared to compare the Lewis basicity of carbonyl-oxygen atoms. In the benzoyl and formyl compounds, the intramolecular C=O···B interacti
Publikováno v:
Bulletin of the Chemical Society of Japan. 73:2357-2362
The structure and stereochemistry of the title organoboron compound, prepared from the corresponding organolithium compound and BCl3, were studied by spectroscopic methods and molecular orbital calculations. The X-ray crystal structure analysis shows
Publikováno v:
Bulletin of the Chemical Society of Japan. 73:205-213
The substituent effect on the rotational barriers of acetylenic to tetrahedral C-C bonds was studied for the title compounds carrying Me or OMe substituents at the 1,4-positions in the 9-triptycyl groups. These compounds were prepared by use of the D
Autor:
Tsutomu Hidaka, Shinji Toyota, Nobuo Nakamura, Mitsuhiro Asakura, Hirotaka Ozaki, Kei Kaneko, Tomoyo Ishiguro, Michinori Oki, Takanori Hirose
Publikováno v:
Bulletin of the Chemical Society of Japan. 72:2327-2336
The title radical rotamers were generated by thermolyses of the corresponding t-butyl peroxycarboxylates or photolyses of the corresponding 2(1H)-thioxo-1-pyridyl carboxylates. Products from the t-butyl peroxyesters were t-butoxy compounds, dimers, a
Publikováno v:
Bulletin of the Chemical Society of Japan. 72:1879-1885
Rates of the dissociation of the intramolecular B–N coordination bond in two series of phenylborane derivatives, the boronate and diethylborane complexes, with –CHMeNMe2 or –CMe2NMe2 group at the o-position were determined by the NMR lineshape
Autor:
Keisuke Kitahara, Michinori O¯ki, Shinji Toyota, Mitsuhiro Asakura, Nobuhiro Morita, Takanori Hirose
Publikováno v:
Tetrahedron Letters. 39:8877-8880
Oxidation of allyl phenyl selenide withm-chloroperoxybenzoic acid unexpectedly afforded two compounds, the structures of which were determined as 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)-3-(phenylseleno)propan-1-o
Autor:
Mitsuhiro Asakura, Yuko Igarashi, Shinji Toyota, Michinori Oki, Akihiro Yasutomi, Hiroharu Kojima
Publikováno v:
Bulletin of the Chemical Society of Japan. 71:2715-2720
The title compound was prepared by addition of 4,5-dimethoxybenzyne to 9,9′-bianthryl. The rotational isomers, ap and ±sc, were separated by HPLC. The ±sc isomers were treated with sodium ethanethiolate to produce 3,3′-dihydroxy-2,2′-dimethox
Publikováno v:
Organometallics. 17:4155-4163
To distinguish between dissociation of a B−N coordination bond by SN1- and SN2-type mechanisms, two series of 1,3,2-dioxaborolanes (boronates) and BEt2 (borane) complexes carrying a 2,6-bis((dimeth...