Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Miriam V. Bennett"'
Publikováno v:
Journal of the American Chemical Society. 132:3980-3988
An S = 3/2, high-anisotropy building unit, trans-[ReCl(4)(CN)(2)](2-), representing the first paramagnetic complex with a mixture of just cyanide and halide ligands, has been synthesized through the reaction of (Bu(4)N)CN with ReCl(4)(THF)(2). This s
Publikováno v:
Inorganica Chimica Acta. 359:1427-1434
A new method for the synthesis of metal dithiolenes with alkyl-substituted chelate rings has been investigated. The utility of the protected ene-1,2-dithiolate 3,4-bis-triisopropylsilanyl-sulfanyl-hex-3-ene as a precursor in reactions with metal hali
Publikováno v:
Journal of the American Chemical Society. 122:6664-6668
A technique for increasing the porosity in solid structures by replacing octahedral metal ions with hexanuclear cluster cores is extended with the expansion of the ion-exchange material Na2Zn3[Fe(CN)6]2·9H2O. At high relative cluster concentrations,
Publikováno v:
ChemInform. 44
Compounds (III) and (V) are characterized by single crystal XRD, diffuse reflectance, and 1H NMR spectroscopy.
Publikováno v:
Chemical communications (Cambridge, England). 49(44)
The [(Cl3Ga)3N](3-) (1) anion, which is the sole example of a discrete chemical species containing a μ3-N atom bound only to gallium, was isolated from the reaction of Cl3Ga·N(SnMe3)3 with [GaCl4](1-). The analogous reaction of [GaCl4](1-) with (Me
Publikováno v:
ChemInform. 41
Publikováno v:
ChemInform. 32
Face-capped octahedral [Re6Se8(CN)6]3-/4- clusters are used in place of octahedral [M(CN)6]3-/4- complexes for the synthesis of microporous Prussian blue type solids with adjustable porosity. The reaction between [Fe(H2O)6]3+ and [Re6Se8(CN)6]4- in a
Autor:
Richard H. Holm, Miriam V. Bennett
Publikováno v:
ChemInform. 37
Publikováno v:
Dalton transactions (Cambridge, England : 2003). (23)
The diamagnetic complex [Re(CN)8]3- is shown to react with Mn2+ ions in methanol to generate the centered, face-capped octahedral cluster (CH3OH)24Mn9Re6(CN)48, which is structurally analogous to (CH3OH)24Mn9Mo6(CN)48. Related reactions involving sto
Publikováno v:
ChemInform. 36