Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Milan Kr. Barman"'
Publikováno v:
Journal of Organometallic Chemistry. 887:40-47
Mixed guanidinato-amido supported complexes of calcium, LCaN(SiMe3)2∙2THF (1) [L = {ArNC(NiPr2)NAr} (Ar = 2,6-Me2-C6H3)] and zinc, LZnN(SiMe3)2 (2) & L1ZnN(SiMe3)2 (3) [L1 = {Ar'NC(NiPr2)NAr'} (Ar' = 2,6- iPr2-C6H3)] have been synthesized by salt m
Publikováno v:
ChemistrySelect. 1:498-503
Herein we report a library of N-heterocyclic carbene-carbodiimide (“NHC-CDI”) adducts i. e., zwitterionic type amidinates from the reaction between N,N’ -diaryl substituted symmetrical or unsymmetrical carbodiimide and N-heterocyclic carbene at
Publikováno v:
New Journal of Chemistry. 40:7627-7636
A metal-free synthesis of symmetrical and unsymmetrical bulky N,N′-diaryl carbodiimides from the dehydrosulfurisation of their corresponding N,N′-diarylthiourea with 4-dimethylaminopyridine (DMAP) and iodine under mild reaction conditions with mo
Publikováno v:
Green Chemistry. 18:2534-2541
A reaction between two equivalents of bulky thiourea, i.e., 1,3-bis(2,6-dimethylphenyl)thiourea (L) [L = (ArNH)2C = S; Ar = 2,6-Me2C6H3], and CuCl2 or CuCl in THF solvent afforded a bulky thiourea-stabilized copper(I) halide complex, LCu(Cl)L (1). Co
Autor:
Milan Kr. Barman, Sharanappa Nembenna
Publikováno v:
RSC Advances. 6:338-345
The first bulky guanidinate supported germathioamide [{ArNC(NiPr2)NAr}GeN(SiMe3)2(S)]; (Ar = 2,6-Me2–C6H3) (3) and germaselanoamide [{ArNC(NiPr2)NAr}GeN(SiMe3)2(Se)] (4) complexes with GeS (3) and GeSe (4) moieties, have been synthesized and struct
Publikováno v:
Journal of Organometallic Chemistry. 785:52-60
Bulky guanidinate stabilized homoleptic complexes of [LM(thf)nL] [L = {ArNC (NiPr2)NAr} (Ar = 2,6- Me2–C6H3)]; M = Mg, Ca, and Zn; n = 0–1) have been synthesized with three different synthetic routes. First, treatment of bis{bis(trimethylsilyl)am
Publikováno v:
Journal of Organometallic Chemistry. :265-270
Two different synthetic routes for the preparation of guanidinate stabilized germanium(II) and tin(II) amide complexes have been established. First, the reaction of one equiv of bulky guanidine ligand either L1H or L2H [L1 = {ArNC (NiPr2)NAr} (Ar = 2
Publikováno v:
Inorganic chemistry. 56(16)
A series of structurally characterized magnesium and zinc complexes of the form L4-tBuPh–M{N(SiMe3)2}2 [M = Mg (1) and Zn (2); L4-tBuPh = 1,3-diethyl-4,5-dimethylimidazolium-2-{N,N′-bis(4-tert-butylphenyl)amidinate}], L4-iPrPh–M{N(SiMe3)2}2 [M
Autor:
Milan Kr. Barman, Cem B. Yildiz, Thangavel Vijayakanth, Ramamoorthy Boomishankar, Vadapalli Chandrasekhar, Anukul Jana, Nicolas Chrysochos, Debabrata Dhara, Carola Schulzke, Khevath Praveen Kumar Naik
A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(iv)-precursor is reported. It has been employed for the addition of an O-H bond of water under ambient conditions without any addi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::25aefab277939e3c55076e5cedc5111a
https://hdl.handle.net/20.500.12451/2338
https://hdl.handle.net/20.500.12451/2338
Publikováno v:
Journal of Organometallic Chemistry. 769:112-118
The catalytic activity of N-heterocyclic carbene (NHC) supported magnesium(II) and a zinc(II) amide complex towards the addition of N–H bond of amine to carbodiimide was studied. Treatment of a free carbene i.e., 1,3-di-tert-butylimidazol-2-ylidene