Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution

Autor: Ulrich Hintermair, Robert H. Crabtree, Daria L. Huang, Sara M. Hashmi, Gary W. Brudvig, Jesús Campos, Menachem Elimelech, Mike Takase, Jonathan Graeupner, Julianne M. Thomsen

Publikováno v: Graeupner, J, Hintermair, U, Huang, D L, Thomsen, J M, Takase, M, Campos, J, Hashmi, S M, Elimelech, M, Brudvig, G W & Crabtree, R H 2013, ' Probing the viability of oxo-coupling pathways in iridium-catalyzed oxygen evolution ', Organometallics, vol. 32, no. 19, pp. 5384–5390 . https://doi.org/10.1021/om400658a

A series of Cp*IrIII dimers has been synthesized to elucidate the mechanistic viability of radical oxo-coupling pathways in iridium-catalyzed O2 evolution. The oxidative stability of the precursors towards nanoparticle formation and their oxygen evol

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https://doi.org/10.1021/om400658a